Dimethylamine
Also known as N-Methylmethanamine, N,N-Dimethylamine, Methanamine, N-methyl-
Key facts
What buyers check first
- Appearance
- Colorless gas
- Melting point
- -93 °C
- Boiling point
- 7.3 °C
- Density
- 0.6804 g/cm³ at 0 °C
- Flash point
- -6.7 °C
- HS code
- 292111
- Category
- Amines and amides
- UN number
- UN 1032
What is Dimethylamine?
Plain description, key identifiers and synonyms
Dimethylamine is a secondary aliphatic amine where both N-substituents are methyl. It has a role as a metabolite. It is a member of methylamines and a secondary aliphatic amine. It is a conjugate base of a dimethylaminium.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- N-methylmethanamine
- CAS number
- 124-40-3 CAS number cross-checkedOther or deprecated CAS: 917-72-6
- EC number
- 204-697-4
- Molecular formula
- C2H7N
- UNII
- ARQ8157E0Q
- MDL number
- MFCD00008288
- InChIKey
- ROSDSFDQCJNGOL-UHFFFAOYSA-N
- InChI
- InChI=1S/C2H7N/c1-3-2/h3H,1-2H3
- SMILES (canonical and isomeric)
- CNC
Synonyms
- N-Methylmethanamine
- N,N-Dimethylamine
- Methanamine, N-methyl-
- Dimethylamine (anhydrous)
- RCRA waste number U092
- Dimethylamine, anhydrous
- methanamine, N-methyl
- Dimethylamine anhydrous
- Dimethylamine-N-d1
- (CH3)2NH
- Dimethylamine aq
- HNMe2
- Me2NH
- Dimethylamine (40% aq.)
- Dimethylamine (~2.0 M in THF)
- Dimethylamine, 40% aqueous solution
- dimethyl amine
- dimethyl-amine
- Dimethylamine solution purum 33% in absolute ethanol (~5.6 M)
- Dimethylamine Hydrochloride-13C2
- RCRA waste no. U092
- dimethlamine
- dimethlyamine
- dimethyamine
- dimethylammonia
Show all 38 synonymsShow fewer synonyms
- dimethylarnine
- dimetylamine
- dirnethylamine
- di-methylamine
- dimetyl amine
- 2 Molar dimethylamine in THF
- Dimethylamine, N-Methylmethanamine, N,N-Dimethylamine, NSC 8650
- N,N-dimethylamin
- N,N dimethylamine
- N,N dimethyl amine
- N,N- dimethylamine
- N,N-dimethyl amine
- N-methyl-Methanamine
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless gasexp.Measured value |
|---|---|
| Odour | Ammonia or fish-like odorexp.Measured value |
| Melting point | -93 °Cexp.Measured value |
| Boiling point | 7.3 °Cexp.Measured value |
| Density | 0.6804 g/cm³ at 0 °Cexp.Measured value |
| Flash point | -6.7 °Cexp.Measured value |
| Autoignition temperature | 400 °Cexp.Measured value |
| Solubility | In water, 163 g/100g water at 40 °Cexp.Measured value |
| Vapour pressure | 1520 mm Hg at 25 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 45.09 g/molcalc.Computed value |
|---|---|
| Exact mass | 45.0578 Dacalc.Computed value |
| LogP (octanol/water) | -0.16calc.Computed value |
| Topological polar surface area | 12.03 Ųcalc.Computed value |
| Hydrogen bond donors | 1calc.Computed value |
| Hydrogen bond acceptors | 1calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 3calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H220Extremely flammable gas.
- H315Causes skin irritation.
- H318Causes serious eye damage.
- H332Harmful if inhaled.
- H335May cause respiratory irritation.
Precautionary statements (22)
- P203Obtain, read and follow all safety instructions before use.
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P222Do not allow contact with air.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
- P271Use only outdoors or in a well-ventilated area.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P302 + P352If on skin: Wash with plenty of water.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P317Get medical help.
- P319Get medical help if you feel unwell.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P332 + P317If skin irritation occurs: Get medical help.
- P362 + P364Take off contaminated clothing. And wash it before reuse.
- P377Leaking gas fire: do not extinguish, unless leak can be stopped safely.
- P381In case of leakage, eliminate all ignition sources.
- P403Store in a well-ventilated place.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1032
- Transport hazard class
- 2.1
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidDimethylamine suppliers
Controlled substance, listings of documented suppliers only, in the documented ranking
Dimethylamine is controlled. Only documented suppliers can list it, and buyers must upload a valid licence with their request. Every request is reviewed before suppliers see it.
Licensed buyers only, every enquiry is reviewed by our compliance team.
Reference: Australia Group export control list, chemical weapons precursor
Our policy on controlled substancesLicensed buyers can post a request for Dimethylamine with their licence. Our compliance team reviews it before suppliers see it.
Dimethylamine price
Indicative price range per kg from live supplier offers
Suppliers quote this chemical on request. Send one free request and compare quotes side by side.
Uses and applications
What the substance is used for, by industry and function
It is used ... for the production of the solvents dimethylformamide (DMF) and dimethylacetamide (DMAC), for water-treating agents, surfactants, rubber-processing compounds, and a range of agrochemicals.
As accelerator in vulcanizing rubber, tanning, manufacturing detergent soaps, or attracting boll weevils to exterminate them (former use). As reagent for magnesium.
Acid-gas absorbent, solvent antioxidants, manufacture of dimethylformamide and dimethylacetamide, dyes, flotation agent, gasoline stabilizers, pharmaceuticals, textile chemicals, rubber accelerators, electroplating, dehairing agent, missile fuels, pesticide propellant, rocket propellants, surfactants, reagent for magnesium.
Use as an antiknock agent in fuels.
Chemical intermediate in pesticide production, solvents, surfactants, rubber processing, and epoxy resin accelerators.
Industrial uses: Binder, Soil amendments (fertilizers), pH regulating agent, Intermediate.
Roles
- metabolite
Functional uses
- Flavouring and nutrient
How it is made
Methylamines are prepared commercially by the exothermic reaction of methanol with ammonia over an amorphous silica-alumina catalyst at 350 - 450 °C. All three methylamines are produced. The reaction proceeds to thermodynamic equilibrium, the position of which is governed by the temperature and the nitrogen/ carbon (NH3/MeOH) ratio. ... In a typical commercial methylamine process ... methanol reacts with ammonia in the gas phase in one or more fixed-bed reactors. The crude reaction mixture contains essentially excess ammonia, mono-, di-, and trimethylamines, reaction water, and unconverted methanol. Purification is generally effected in a train of four to five distillation columns.
Preparation from methanol plus ammonia, ... by catalytic hydrogenation of nitrosodimethylamine.
Regulatory status
Inventories, regulations and trade controls that list this substance
Dimethylamine is controlled. Only documented suppliers can list it, and buyers must upload a valid licence with their request. Every request is reviewed before suppliers see it.
Licensed buyers only, every enquiry is reviewed by our compliance team.
Reference: Australia Group export control list, chemical weapons precursor
Our policy on controlled substancesEurope
- EU harmonised classification (CLP Annex VI)Index no: 612-001-00-9[2]
Health and food
- EU Cosmetics Regulation Annex II, prohibited in cosmeticsName: Dimethylamine, Ref no: 142, Annex ref: II/142
Controls
- Chemical Weapons Convention Schedule 3
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Dimethylamine is traded under.
Methylamine, di- or trimethylamine and their salts
- Belgium33.3%
- South Korea15.1%
- United States13.7%
- Spain7.9%
- Brazil6.4%
- Philippines6.3%
The HS code shown for Dimethylamine is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Dimethylamine, based on the data on this page
What is Dimethylamine?
What is the CAS number of Dimethylamine?
What is the molecular formula and weight of Dimethylamine?
What is Dimethylamine used for?
Is Dimethylamine hazardous?
What is the HS code of Dimethylamine?
Can I buy Dimethylamine on CompoundList?
Guides for buyers
Practical guides that help when you source, ship or handle Dimethylamine
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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