Hydroxypropyl acrylate
Also known as Propylene glycol acrylate, Acrylic acid, hydroxypropyl ester, Acrylic acid, monoester with 1,2-propanediol
Key facts
What buyers check first
- Appearance
- Colorless liquid
- Melting point
- -30 °C
- Boiling point
- 205.7 °C
- Density
- 1.05 g/cm³
- Flash point
- 97 °C
- HS code
- 290532
- Category
- Alcohols and polyols
- UN number
- UN 1760

What is Hydroxypropyl acrylate?
Plain description, key identifiers and synonyms
Hydroxypropyl acrylate appears as a clear colorless liquid. Toxic by inhalation and skin absorption. Corrosive to tissue. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air. Used to make plastics.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- propane-1,2-diol, prop-2-enoic acid
- CAS number
- 25584-83-2 CAS number cross-checked
- EC number
- 247-118-0
- Molecular formula
- C6H12O4
- UNII
- 7EFO911SQH
- InChIKey
- AYEFIAVHMUFQPZ-UHFFFAOYSA-N
- InChI
- InChI=1S/C3H8O2.C3H4O2/c1-3(5)2-4;1-2-3(4)5/h3-5H,2H2,1H3;2H,1H2,(H,4,5)
- SMILES (canonical and isomeric)
- CC(CO)O.C=CC(=O)O
Synonyms
- Propylene glycol acrylate
- Acrylic acid, hydroxypropyl ester
- Acrylic acid, monoester with 1,2-propanediol
- Acrylic acid, monoester with propane-1,2-diol
- 2-Propenoic acid, monoester with 1,2-propanediol
- Viscoat hpa
- propane-1,2-diol, prop-2-enoic acid
- Acrylic acid 2-hydroxypropyl ester
- acrylic acid, propane-1,2-diol
- 1,2(or 3)-Propanediol, 1-acrylate
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless liquidexp.Measured value |
|---|---|
| Odour | Faint unpleasant odorexp.Measured value |
| Melting point | -30 °Cexp.Measured value |
| Boiling point | 205.7 °Cexp.Measured value |
| Density | 1.05 g/cm³exp.Measured value |
| Flash point | 97 °Cexp.Measured value |
| Solubility | Water solubleexp.Measured value |
| Vapour pressure | Vapor pressure, Pa at 25 °C: 4exp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 148.16 g/molcalc.Computed value |
|---|---|
| Exact mass | 148.0736 Dacalc.Computed value |
| LogP (octanol/water) | -0.38calc.Computed value |
| Topological polar surface area | 77.76 Ųcalc.Computed value |
| Hydrogen bond donors | 3calc.Computed value |
| Hydrogen bond acceptors | 3calc.Computed value |
| Rotatable bonds | 2calc.Computed value |
| Heavy atoms | 10calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 0.5calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 1calc.Computed value |
| Components | 2calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H301Toxic if swallowed.
- H311Toxic in contact with skin.
- H314Causes severe skin burns and eye damage.
- H317May cause an allergic skin reaction.
- H331Toxic if inhaled.
Precautionary statements (24)
- P260Do not breathe dust, fume, gas, mist, vapours or spray.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P262Do not get in eyes, on skin, or on clothing.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P272Contaminated work clothing should not be allowed out of the workplace.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P316If swallowed: Get emergency medical help immediately.
- P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
- P302 + P352If on skin: Wash with plenty of water.
- P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316Get emergency medical help immediately.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P330Rinse mouth.
- P333 + P317If skin irritation or rash occurs: Get medical help.
- P361 + P364Take off immediately all contaminated clothing. And wash it before reuse.
- P362 + P364Take off contaminated clothing. And wash it before reuse.
- P363Wash contaminated clothing before reuse.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1760
- Transport hazard class
- 6.1
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidHydroxypropyl acrylate suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- Spain, BarcelonaUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- ManufacturerUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- China, Shenyang ManufacturerUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- China ManufacturerUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- United Kingdom, Bishop's Stortford ManufacturerUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
- China ManufacturerUnclaimed profileHydroxypropyl acrylateGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
22 suppliers in 6 countries
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Hydroxypropyl acrylate price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
Comonomer in adhesives, elastomers, inks, and oil additives, viscosity reducer.
Hydroxypropyl acrylate is mainly used either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates.
For the manufacture of hydrogel contact lenses. (3-Hydroxypropyl acrylate).
Indirect Additives used in Food Contact Substances: HYDROXYPROPYL ACRYLATE.
Hydroxypropyl acrylates, usually as isomer mixtures, are used in the industrial production of acrylate polymers for lacquers and artificial resins, and as a co-monomer in adhesives, elastomers, inks, and oil additives and as a viscosity reducer.
Industrial uses: Monomers.
Consumer uses: Binder.
How it is made
Reaction of acrylic acid and propylene oxide, catalyzed by a base
Acrylate esters can be made by reacting a vinyl halide with carbon monoxide and an organic halide in the presence of a Group VIII catalyst. Also developed is a process that yields acrylate esters after the generation of 2-halo-1-alkenes from hydrocarbon streams. Both processes were developed by Dow Chemical Co.
In ... propylene oxidation process acrolein is first formed by the catalytic oxidation of propylene vapor at high temp in the presence of steam. The acrolein is then oxidized to acrylic acid ... The acrylic acid is esterified with alcohol to the ... acrylic ester in a separate process. (Acrylic ester monomers)
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 607-108-00-2[3]
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Hydroxypropyl acrylate is traded under.
Propylene glycol (propane-1,2-diol)
- Germany19.1%
- China18.0%
- United States10.6%
* Partner reported figures, a lower bound.
The HS code shown for Hydroxypropyl acrylate is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Hydroxypropyl acrylate, based on the data on this page
What is Hydroxypropyl acrylate?
What is the CAS number of Hydroxypropyl acrylate?
What is the molecular formula and weight of Hydroxypropyl acrylate?
What is Hydroxypropyl acrylate used for?
Is Hydroxypropyl acrylate hazardous?
What is the HS code of Hydroxypropyl acrylate?
Where can I buy Hydroxypropyl acrylate?
What is the price of Hydroxypropyl acrylate?
Guides for buyers
Practical guides that help when you source, ship or handle Hydroxypropyl acrylate
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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