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Hydroxypropyl acrylate

Also known as Propylene glycol acrylate, Acrylic acid, hydroxypropyl ester, Acrylic acid, monoester with 1,2-propanediol

Hydroxypropyl acrylate chemical structure, C6H12O4, CAS 25584-83-2
2D chemical structure

Key facts

What buyers check first

Appearance
Colorless liquid
Melting point
-30 °C
Boiling point
205.7 °C
Density
1.05 g/cm³
Flash point
97 °C
HS code
290532
Category
Alcohols and polyols
UN number
UN 1760
Illustrative photo, 200 litre steel drums of liquid in a chemical plant
Typical packagingIllustrative packaging image, not the actual product

What is Hydroxypropyl acrylate?

Plain description, key identifiers and synonyms

Hydroxypropyl acrylate appears as a clear colorless liquid. Toxic by inhalation and skin absorption. Corrosive to tissue. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air. Used to make plastics.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
propane-1,2-diol, prop-2-enoic acid
CAS number
25584-83-2 CAS number cross-checked
EC number
247-118-0
Molecular formula
C6H12O4
UNII
7EFO911SQH
InChIKey
AYEFIAVHMUFQPZ-UHFFFAOYSA-N
InChI
InChI=1S/C3H8O2.C3H4O2/c1-3(5)2-4;1-2-3(4)5/h3-5H,2H2,1H3;2H,1H2,(H,4,5)
SMILES (canonical and isomeric)
CC(CO)O.C=CC(=O)O

Synonyms

  • Propylene glycol acrylate
  • Acrylic acid, hydroxypropyl ester
  • Acrylic acid, monoester with 1,2-propanediol
  • Acrylic acid, monoester with propane-1,2-diol
  • 2-Propenoic acid, monoester with 1,2-propanediol
  • Viscoat hpa
  • propane-1,2-diol, prop-2-enoic acid
  • Acrylic acid 2-hydroxypropyl ester
  • acrylic acid, propane-1,2-diol
  • 1,2(or 3)-Propanediol, 1-acrylate

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
Colorless liquidexp.
Odour
Faint unpleasant odorexp.
Melting point
-30 °Cexp.
Boiling point
205.7 °Cexp.
Density
1.05 g/cm³exp.
Flash point
97 °Cexp.
Solubility
Water solubleexp.
Vapour pressure
Vapor pressure, Pa at 25 °C: 4exp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
148.16 g/molcalc.
Exact mass
148.0736 Dacalc.
LogP (octanol/water)
-0.38calc.
Topological polar surface area
77.76 Ųcalc.
Hydrogen bond donors
3calc.
Hydrogen bond acceptors
3calc.
Rotatable bonds
2calc.
Heavy atoms
10calc.
Rings
0calc.
Aromatic rings
0calc.
Fraction sp3 carbons
0.5calc.
Formal charge
0calc.
Stereocentres
1calc.
Components
2calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Danger
GHS05: Corrosive
Corrosive
GHS06: Acute toxicity (severe)
Acute toxicity (severe)
132NFPA 704 rating

Hazard statements

  • H301Toxic if swallowed.
  • H311Toxic in contact with skin.
  • H314Causes severe skin burns and eye damage.
  • H317May cause an allergic skin reaction.
  • H331Toxic if inhaled.
Precautionary statements (24)
  • P260Do not breathe dust, fume, gas, mist, vapours or spray.
  • P261Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P262Do not get in eyes, on skin, or on clothing.
  • P264Wash skin thoroughly after handling.
  • P270Do not eat, drink or smoke when using this product.
  • P271Use only outdoors or in a well-ventilated area.
  • P272Contaminated work clothing should not be allowed out of the workplace.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.
  • P301 + P316If swallowed: Get emergency medical help immediately.
  • P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
  • P302 + P352If on skin: Wash with plenty of water.
  • P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
  • P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P316Get emergency medical help immediately.
  • P321Specific treatment (see supplemental first aid instructions on the label).
  • P330Rinse mouth.
  • P333 + P317If skin irritation or rash occurs: Get medical help.
  • P361 + P364Take off immediately all contaminated clothing. And wash it before reuse.
  • P362 + P364Take off contaminated clothing. And wash it before reuse.
  • P363Wash contaminated clothing before reuse.
  • P403 + P233Store in a well-ventilated place. Keep container tightly closed.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 1760
Transport hazard class
6.1
Packing group
II

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

Hydroxypropyl acrylate suppliers

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Hydroxypropyl acrylate price

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Uses and applications

What the substance is used for, by industry and function

Comonomer in adhesives, elastomers, inks, and oil additives, viscosity reducer.

Hydroxypropyl acrylate is mainly used either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates.

For the manufacture of hydrogel contact lenses. (3-Hydroxypropyl acrylate).

Indirect Additives used in Food Contact Substances: HYDROXYPROPYL ACRYLATE.

Hydroxypropyl acrylates, usually as isomer mixtures, are used in the industrial production of acrylate polymers for lacquers and artificial resins, and as a co-monomer in adhesives, elastomers, inks, and oil additives and as a viscosity reducer.

Industrial uses: Monomers.

Consumer uses: Binder.

How it is made

Reaction of acrylic acid and propylene oxide, catalyzed by a base

Acrylate esters can be made by reacting a vinyl halide with carbon monoxide and an organic halide in the presence of a Group VIII catalyst. Also developed is a process that yields acrylate esters after the generation of 2-halo-1-alkenes from hydrocarbon streams. Both processes were developed by Dow Chemical Co.

In ... propylene oxidation process acrolein is first formed by the catalytic oxidation of propylene vapor at high temp in the presence of steam. The acrolein is then oxidized to acrylic acid ... The acrylic acid is esterified with alcohol to the ... acrylic ester in a separate process. (Acrylic ester monomers)

Regulatory status

Inventories, regulations and trade controls that list this substance

Europe

  • EU harmonised classification (CLP Annex VI)
    Index no: 607-108-00-2[3]

United States

  • TSCA inventory (USA)
    Status: Active in US commerce

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code Hydroxypropyl acrylate is traded under.

HS 2905.32Indicative HS code

Propylene glycol (propane-1,2-diol)

World exports in 2024
$1.44B
−3.3% vs 2023, imports $1.4B
2019 to 2024
Top exporters
  1. Germany19.1%
  2. China18.0%
  3. United States10.6%
Top importers
  1. India * partner reported7.8%
  2. France * partner reported6.1%
  3. China5.3%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for Hydroxypropyl acrylate is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about Hydroxypropyl acrylate, based on the data on this page

What is Hydroxypropyl acrylate?

Hydroxypropyl acrylate appears as a clear colorless liquid. Toxic by inhalation and skin absorption. Corrosive to tissue. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air. Used to make plastics.

What is the CAS number of Hydroxypropyl acrylate?

The CAS registry number of Hydroxypropyl acrylate is 25584-83-2.

What is the molecular formula and weight of Hydroxypropyl acrylate?

The molecular formula of Hydroxypropyl acrylate is C6H12O4 and its molar mass is 148.16 g/mol.

What is Hydroxypropyl acrylate used for?

Comonomer in adhesives, elastomers, inks, and oil additives, viscosity reducer. Hydroxypropyl acrylate is mainly used either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. For the manufacture of hydrogel contact lenses. (3-Hydroxypropyl acrylate).

Is Hydroxypropyl acrylate hazardous?

Hydroxypropyl acrylate carries the GHS signal word "Danger". Main hazards: toxic if swallowed, toxic in contact with skin, causes severe skin burns and eye damage. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of Hydroxypropyl acrylate?

Hydroxypropyl acrylate is usually classified under HS code 290532 (Propylene glycol (propane-1,2-diol)). This is indicative, confirm it with your customs broker before shipping.

Where can I buy Hydroxypropyl acrylate?

CompoundList lists 22 suppliers of Hydroxypropyl acrylate in China, United States, Netherlands, Spain and 2 more. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

What is the price of Hydroxypropyl acrylate?

Suppliers quote Hydroxypropyl acrylate on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle Hydroxypropyl acrylate

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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