Phosphorus
Also known as Phosphorus 6, Phosphorus 8, Phosphorus 6C
Key facts
What buyers check first
- Appearance
- Exists in three main allotropic forms: white, black, and red. The same liquid is obtaine…
- Melting point
- 44.1 °C
- Boiling point
- 280 °C
- Density
- 1.74 g/cm³ at 50 °C (liquid)
- Solubility
- Black: Insoluble in organic solvents, White: Insoluble in water, slightly soluble in ben…
- HS code
- 280470
- Category
- Metals, alloys and elements
- UN number
- UN 1381

What is Phosphorus?
Plain description, key identifiers and synonyms
Phosphorus is an element with atomic symbol P, atomic number 15, and atomic weight 30.97.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- phosphane
- CAS number
- 7723-14-0 CAS number cross-checkedOther or deprecated CAS: 12185-10-3
- EC number
- 231-768-7
- Molecular formula
- P
- UNII
- 27YLU75U4W
- INCI name
- PHOSPHORUS
- InChIKey
- OAICVXFJPJFONN-UHFFFAOYSA-N
- InChI
- InChI=1S/P
- SMILES (canonical and isomeric)
- [P]
Synonyms
- Phosphorus 6
- Phosphorus 8
- Phosphorus 6C
- Phosphorus 30
- Phosphorus 30C
- Phosphorus 30X
- Phosphorus 31
- Cough Sore Throat
- Phosphorus 200C
- Phosphorus 200ck
- Phosphorous (NOS)
- Phosphorus 7130
- Phosphorus 30 Special Order
- Bestmade Natural Products Phosphorus
- Amgard CPC
- Amgard CPC 405
- Exolit 385
- Exolit 405
- Exolit LPKN 275
- Hishigado
- Hishigado AP
- Hishigado CP
- Hishigado NP 10
- Hostaflam RP 602
- Hostaflam RP 614
Show all 39 synonymsShow fewer synonyms
- Hostaflam RP 622
- Hostaflam RP 654
- Nova Sol R 20
- Novaexcel 140
- Novaexcel 150
- Novaexcel F 5
- Novaexcel ST 100
- Novaexcel ST 140
- Novared 120UF
- Novared 120UFA
- Novared 120VFA
- Novared 280
- Novared C 120
- Phosphorous
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Exists in three main allotropic forms: white, black, and red. The same liquid is obtained from all forms on meltingexp.Measured value |
|---|---|
| Odour | Garlic-likeexp.Measured value |
| Melting point | 44.1 °Cexp.Measured value |
| Boiling point | 280 °Cexp.Measured value |
| Density | 1.74 g/cm³ at 50 °C (liquid)exp.Measured value |
| Autoignition temperature | 260 °Cexp.Measured value |
| Solubility | Black: Insoluble in organic solvents, White: Insoluble in water, slightly soluble in benzene, ethanol, and chloroform, soluble in carbon disulfide, Red: Insoluble in water and organic solvents.exp.Measured value |
| Vapour pressure | 0.026 mm Hg at 20 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 30.97 g/molcalc.Computed value |
|---|---|
| Exact mass | 30.9738 Dacalc.Computed value |
| LogP (octanol/water) | 0.86calc.Computed value |
| Topological polar surface area | 0 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 0calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 1calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 0calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H228Flammable solid.
- H412Harmful to aquatic life with long lasting effects.
Precautionary statements (7)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P273Avoid release to the environment.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1381
- Transport hazard class
- 4.2
- Packing group
- I
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidPhosphorus suppliers
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- ChinaUnclaimed profilePhosphorusGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
30 suppliers in 10 countries
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Phosphorus price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
The active ingredient is no longer contained in any registered pesticide products ... "cancelled.".
White phosphorus has been used as insecticide in pastes made by grinding yellow phosphorus in presence of water and mixing with flour. Phosphorus paste was used to control American cockroach, also as rat poison.
Most (85%) of the elemental phosphorus is converted to phosphoric acid which is used directly or converted to phosphate compounds. Final applications include home laundry and automatic dishwasher detergents, industrial and institutional cleaners, food and beverages, metal cleaning and treatment, potable water and wastewater treatment, antifreeze and electronics.
Read more
The remaining elemental phosphorus (15%) is used in P4-dependent applications which require the element as a direct reactant (P2S5, PCl3, POCl3, P2O5, and hypophosphite with smaller amounts leading to PH3, red phosphorus, phosphonates and other derivatives). Final applications include flame retardants, lubricant additives, insecticides, herbicides, water treatment, cleaning compounds, plasticizers, semiconductors, and surfactants.
White phosphorus is a toxic substance produced from phosphate-containing rocks. Industries use white phosphorus to manufacture chemicals used in fertilizers, food additives, and cleaning compounds. In the past, it was used as a pesticide and in fireworks. The military uses white phosphorus in various types of ammunition as an incendiary agent, because it spontaneously catches fire in air. They also use it as a smoke agent, because it produces clouds of irritating white smoke. It has a match-like or garlic-like, acrid odor, but do not depend on odor for detection of white phosphorus.
Industries and functions
Cosmetic ingredient, INCI name PHOSPHORUS(not reported)
Roles
- food component
- macronutrient
- nutrient
- physiological role
Functional uses
- Alloying element
- Antioxidant
- Flame retardant
Cosmetic functions
- Not reported
How it is made
White phosphorus: (1) Produced in an electric furnace from phosphate rock, sand, and coke. The phosphorus vapor is driven off and condensed under water. (2) By reaction of phosphate rock with sulfuric acid, the resulting calcium sulfate being removed by filtration and the phosphoric acid concentrated by evaporation (wet process).
Red phosphorus is produced by heating white crystalline phosphorus to about 400 °C under an atmosphere of an oxygen-free inert gas, such as nitrogen or argon.
Black phosphorus: Produced from the white modification under high pressures.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 015-002-00-7
Health and food
- EU cosmetic ingredient inventory
- EU Cosmetics Regulation Annex II, prohibited in cosmeticsName: Phosphorus and metalphosphides, Ref no: 279, Annex ref: II/279
- Active ingredient in FDA approved drug labels
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Phosphorus is traded under.
Phosphorus
- Vietnam * partner reported44.1%
- Kazakhstan * partner reported32.5%
- United States13.8%
- Japan17.1%
- Germany17.1%
- South Korea13.2%
* Partner reported figures, a lower bound.
The HS code shown for Phosphorus is indicative (it was matched by name in the HS nomenclature). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Phosphorus, based on the data on this page
What is Phosphorus?
What is the CAS number of Phosphorus?
What is the molecular formula and weight of Phosphorus?
What is Phosphorus used for?
Is Phosphorus hazardous?
What is the HS code of Phosphorus?
Where can I buy Phosphorus?
Where can I buy Phosphorus in India?
What is the price of Phosphorus?
Guides for buyers
Practical guides that help when you source, ship or handle Phosphorus
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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