Acenaphthene
Also known as 1,2-Dihydroacenaphthylene, 1,8-Ethylenenaphthalene, peri-Ethylenenaphthalene
Key facts
What buyers check first

What is Acenaphthene?
Plain description, key identifiers and synonyms
Acenaphthene is a polycyclic aromatic hydrocarbon derived from naphthalene by the addition of an ethylene bridge connecting C-1 and C-8.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- 1,2-dihydroacenaphthylene
- CAS number
- 83-32-9 CAS number cross-checked
- EC number
- 201-469-6
- Molecular formula
- C12H10
- UNII
- V8UT1GAC5Y
- MDL number
- MFCD00003807
- InChIKey
- CWRYPZZKDGJXCA-UHFFFAOYSA-N
- InChI
- InChI=1S/C12H10/c1-3-9-4-2-6-11-8-7-10(5-1)12(9)11/h1-6H,7-8H2
- SMILES (canonical and isomeric)
- C1CC2=CC=CC3=C2C1=CC=C3
Synonyms
- 1,2-Dihydroacenaphthylene
- 1,8-Ethylenenaphthalene
- peri-Ethylenenaphthalene
- Naphthyleneethylene
- Acenaphthylene, 1,2-dihydro-
- Ethylenenaphthalene
- 1,8-Dihydroacenaphthalene
- Periethylenenaphthalene
- 1,8-Dihydroacenaphthylene
- acenapthene
- Acenaphthene (1,2-Dihydro Acenaphthylene)
- Acenaphthene, 1,2-Dihydroacenaphthylene, peri-Ethylenenaphthalene, 1,8-Ethylenenaphthalene
- Acenaphthene, 97%
- Acenaphthene, 99%
- Acenaphthene,
- 1,2-dihydro-acenaphthylene
- Naphthalene, 1,8-ethylene-
- Acenaphthene, analytical standard
- Acenaphthene 10 microg/mL in Acetonitrile
- Acenaphthene 100 microg/mL in Acetonitrile
- Acenaphthene Zone Refined (number of passes:30)
- 07C - Polycyclic Aromatic Hydrocarbons (2 Spikes)
- 19C - Polycyclic Aromatic Hydrocarbons (2 Spikes)
- Acenaphthene, certified reference material, TraceCERT(R)
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | White needlesexp.Measured value |
|---|---|
| Melting point | 93 °Cexp.Measured value |
| Boiling point | 277.5 °Cexp.Measured value |
| Density | 1.222 g/cm³ at 20 °Cexp.Measured value |
| Flash point | 125 °Cexp.Measured value |
| Autoignition temperature | >450exp.Measured value |
| Solubility | In water, 3.90 mg/L at 25 °Cexp.Measured value |
| Vapour pressure | 0.0022 mm Hg at 25 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 154.21 g/molcalc.Computed value |
|---|---|
| Exact mass | 154.0783 Dacalc.Computed value |
| LogP (octanol/water) | 2.94calc.Computed value |
| Topological polar surface area | 0 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 0calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 12calc.Computed value |
| Rings | 3calc.Computed value |
| Aromatic rings | 2calc.Computed value |
| Fraction sp3 carbons | 0.17calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Murcko scaffold
The ring system that remains when every side chain is removed
c1cc2c3c(cccc3c1)CC2
3 rings, 12 atoms. This chemical is the scaffold itself.
250 other chemicals share this scaffoldSafety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H319Causes serious eye irritation.
- H400Very toxic to aquatic life.
- H410Very toxic to aquatic life with long lasting effects.
Precautionary statements (7)
- P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
- P273Avoid release to the environment.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P337 + P317If eye irritation persists: Get medical help.
- P391Collect spillage.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 3082
- Transport hazard class
- 9
- Packing group
- III
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidAcenaphthene suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- United StatesUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- China, AnshanUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- India, Panchkula ManufacturerUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- China, AnshanUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- India, Mumbai ManufacturerUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- United Arab Emirates, Dubai ManufacturerUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- India, GurugramUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
- Price on request
- India, MumbaiUnclaimed profileAcenaphtheneGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
44 suppliers in 12 countries
- China15
- India8
- United States6
- Hong Kong3
- Czech Republic2
- United Arab Emirates1
- and 6 more countries
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Acenaphthene price
Indicative price range per kg from live supplier offers
Suppliers quote this chemical on request. Send one free request and compare quotes side by side.
Uses and applications
What the substance is used for, by industry and function
Dye intermediate, manufacturing plastics, insecticide, fungicide.
Pharmaceuticals.
Industries and functions
Functional uses
- Dye
How it is made
High-temperature coal tars contain on average 0.3% of acenaphthene. It is also formed during coal tar distillation through hydrogenation of acenaphthalene. Acenaphthene is concentrated to ca. 25% in the coal tar fraction boiling between 230 and 290 °C (wash oil) with about 7% recovery rate from continuous tar distillation. The crystallizable acenaphthene fraction (bp ca. 270-275 °C) is obtained from the wash oil by redistillation. Alternatively, it can be removed directly during primary tar distillation.
Read more
Technical acenaphthene (95-99%) is produced by crystallization in agitated coolers and centrifuges or by continuous countercurrent crystallization. The pure compound is obtained by further distillation and recrystallization.
By passing ethylene and benzene or naphthalene through a red hot tube. ... By heating tetrahydroacenaphthene with sulfur to 180 °C. ... From acenaphthenone or acenaphthenequinone by high pressure hydrogenation in decalin with nickel at 180-240 °C. ... From acenaphthenone oxime.
Regulatory status
Inventories, regulations and trade controls that list this substance
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Acenaphthene is traded under.
Cyclic hydrocarbons, other
- Germany11.1%
- United States10.6%
- South Korea8.3%
* Partner reported figures, a lower bound.
The HS code shown for Acenaphthene is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Acenaphthene, based on the data on this page
What is Acenaphthene?
What is the CAS number of Acenaphthene?
What is the molecular formula and weight of Acenaphthene?
What is Acenaphthene used for?
Is Acenaphthene hazardous?
What is the HS code of Acenaphthene?
Where can I buy Acenaphthene?
Where can I buy Acenaphthene in India?
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Guides for buyers
Practical guides that help when you source, ship or handle Acenaphthene
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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