Cyclohexane
Also known as Hexamethylene, Hexahydrobenzene, Hexanaphthene
Key facts
What buyers check first
- Appearance
- Colorless mobile liquid
- Melting point
- 6.5 °C
- Boiling point
- 80.7 °C
- Density
- Relative density (water = 1): 0.8
- Flash point
- -18 °C
- HS code
- 290211
- Category
- Acid and mordant dyes
- UN number
- UN 1145

What is Cyclohexane?
Plain description, key identifiers and synonyms
Cyclohexane is an alicyclic hydrocarbon comprising a ring of six carbon atoms, the cyclic form of hexane, used as a raw material in the manufacture of nylon. It has a role as a non-polar solvent. It is a volatile organic compound and a cycloalkane.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- cyclohexane
- CAS number
- 110-82-7 CAS number cross-checkedOther or deprecated CAS: 12217-02-6
- EC numbers
- 203-806-2, 601-849-5
- Molecular formula
- C6H12
- UNII
- 48K5MKG32S
- MDL number
- MFCD00003814
- INCI name
- CYCLOHEXANE
- InChIKey
- XDTMQSROBMDMFD-UHFFFAOYSA-N
- InChI
- InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
- SMILES (canonical and isomeric)
- C1CCCCC1
Synonyms
- Hexamethylene
- Hexahydrobenzene
- Hexanaphthene
- Cyclohexan
- Cykloheksan
- Benzene, hexahydro-
- Cicloesano
- Cyclohexaan
- Benzenehexahydride
- RCRA waste number U056
- Benzene hexahydride
- hexahydro-Benzene
- cyclo-hexane
- Acid red 300
- Cyclohexane, HPLC Grade
- Ciclohexano
- Cyclohexane, ACS reagent, >=99%
- Cyclohexane, for HPLC, >=99.7%
- RCRA waste no. U056
- cylcohexane
- cylohexane
- Zyklohexan
- Cyclohexane HPLC grade
- Cyclohexane, for HPLC
- Cyclohexane, ACS Grade
Show all 29 synonymsShow fewer synonyms
- Cyclohexane- d12
- ghl.PD_Mitscher_leg0.242
- Cyclohexane, LR, >=99%
- Cyclohexane, JIS special grade
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless mobile liquidexp.Measured value |
|---|---|
| Odour | Solvent odor, pungent when impureexp.Measured value |
| Melting point | 6.5 °Cexp.Measured value |
| Boiling point | 80.7 °Cexp.Measured value |
| Density | Relative density (water = 1): 0.8exp.Measured value |
| Flash point | -18 °Cexp.Measured value |
| Autoignition temperature | 245 °Cexp.Measured value |
| Solubility | In water, 55 mg/L at 25 °Cexp.Measured value |
| Vapour pressure | 13.0 kPa at 25 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 84.16 g/molcalc.Computed value |
|---|---|
| Exact mass | 84.0939 Dacalc.Computed value |
| LogP (octanol/water) | 2.34calc.Computed value |
| Topological polar surface area | 0 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 0calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 6calc.Computed value |
| Rings | 1calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Murcko scaffold
The ring system that remains when every side chain is removed
C1CCCCC1
1 ring, 6 atoms. This chemical is the scaffold itself.
24,737 other chemicals share this scaffoldSafety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H225Highly flammable liquid and vapour.
- H304May be fatal if swallowed and enters airways.
- H315Causes skin irritation.
- H336May cause drowsiness or dizziness.
- H400Very toxic to aquatic life.
- H410Very toxic to aquatic life with long lasting effects.
Precautionary statements (26)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P233Keep container tightly closed.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P242Use non-sparking tools.
- P243Take action to prevent static discharges.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P271Use only outdoors or in a well-ventilated area.
- P273Avoid release to the environment.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P316If swallowed: Get emergency medical help immediately.
- P302 + P352If on skin: Wash with plenty of water.
- P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P319Get medical help if you feel unwell.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P331Do not induce vomiting.
- P332 + P317If skin irritation occurs: Get medical help.
- P362 + P364Take off contaminated clothing. And wash it before reuse.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P391Collect spillage.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P403 + P235Store in a well-ventilated place. Keep cool.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1145
- Transport hazard class
- 3
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidCyclohexane suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- India, ChennaiUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- United States, West Palm BeachUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- United States, Powell ManufacturerUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- Spain, BarcelonaUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- Spain, MadridUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- Spain, BarcelonaUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- Belgium, AntwerpenUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- India, Panchkula ManufacturerUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- China, QingdaoUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
- United States, Fort Worth ManufacturerUnclaimed profileCyclohexaneGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
358 suppliers in 42 countries
- United States106
- India78
- China70
- United Kingdom12
- Germany9
- Japan6
- and 36 more countries
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Cyclohexane price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
Organic solvent for lacquers and resins. Paint and varnish remover. In the extraction of essential oils. In analytical chemistry for molecular weight determinations (cryoscopic constant 20.3). In the manufacturing of adipic acid, benzene, cyclohexyl chloride, nitrocyclohexane, cyclohexanol and cyclohexanone. In the manufacturing of solid fuel for camp stoves. In fungicidal formulations (possesses slight fungicidal action). In the industrial recrystallization of steroids.
Manufacture of nylon, solvent for cellulose ethers, fats, oils, waxes, bitumens, resins, crude rubber, extraction essential oils, organic synthesis, paint and varnish removers, glass substitutes.
Over 98% of the cyclohexane produced is used to make nylon intermediates: adipic acid (60%), caprolactam, and hexamethylenediamine 75% of the caprolactam produced worldwide is used for nylon 6 manufacture.
Read more
Minor miscellaneous uses, such as solvents and polymer reaction diluents, consume the remainder of the cyclohexane produced.
Industrial uses: Solvent, Processing aids not otherwise specified, Fuel, Fuel agents, Catalyst, Drier, Intermediate.
Consumer uses: Fuel agents, Fuel, Solvent, Intermediate, Laboratory chemicals.
Use classes: Cosmetics.
Industries and functions
Cosmetic ingredient, INCI name CYCLOHEXANE(solvent)
Roles
- non-polar solvent
- solvent
Functional uses
- Cleaning agent
- Defoamer
- Fragrance
- Solvent
Cosmetic functions
- Solvent
How it is made
Benzene can be hydrogenated catalytically to cyclohexane in either the liquid or the vapor phase in the presence of hydrogen. Several cyclohexane processes, which use nickel, platinum, or palladium as the catalyst, have been developed. Usually, the catalyst is supported, e.g., on alumina, but at least one commercial process utilizes Raney nickel.
Occurs in petroleum (0.5-1.0%). Obtained in the distillation of petroleum ...
Read more
In distillation of petroleum the C4-400 °F boiling range naphthas are fractionated to obtain C5-200 °F naphtha containing 10-14% cyclohexane which on superfractionation yields an 85% concentrate (which is sold as such), further purification (of 85% concentrate cyclohexane) necessitates isomerization of pentanes to cyclohexane, heat cracking for removing open chain hydrocarbons and sulfuric acid treatment to remove aromatic compounds.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 601-017-00-1
Health and food
- EU cosmetic ingredient inventory
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Cyclohexane is traded under.
Cyclic hydrocarbons: cyclohexane
- Saudi Arabia29.6%
- United States15.5%
- Netherlands14.6%
* Partner reported figures, a lower bound.
The HS code shown for Cyclohexane is indicative (it was matched by name in the HS nomenclature). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Cyclohexane, based on the data on this page
What is Cyclohexane?
What is the CAS number of Cyclohexane?
What is the molecular formula and weight of Cyclohexane?
What is Cyclohexane used for?
Is Cyclohexane hazardous?
What is the HS code of Cyclohexane?
Where can I buy Cyclohexane?
Where can I buy Cyclohexane in India?
What is the price of Cyclohexane?
Guides for buyers
Practical guides that help when you source, ship or handle Cyclohexane
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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