Cyclohexanone peroxide
Also known as Perhexa P, 1-Hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide, Cyclohexanone, peroxide
Key facts
What buyers check first
- Appearance
- Grayish paste
- Melting point
- 76 to 77
- Density
- 1.05 at 68 °F - Denser than water, will sink
- Flash point
- 157.2 °C
- Solubility
- OFF-WHITE THICK PASTE, INSOL IN WATER, SOL IN COMMON ORG SOLVENTS /PASTE WITH DIBUTYL PH…
- HS code
- 290960
- Category
- Initiators, curing agents and crosslinkers
- UN number
- UN 3105

What is Cyclohexanone peroxide?
Plain description, key identifiers and synonyms
1-hydroxy-1'-hydroperoxy dicyclohexyl peroxide is an odorless thick white liquid. Sinks in water. (USCG, 1999)
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol
- CAS number
- 12262-58-7Other or deprecated CAS: 78-18-2
- EC numbers
- 201-091-1, 235-527-7
- Molecular formula
- C12H22O5
- UNII
- 3P1S15N7AV
- InChIKey
- UICXTANXZJJIBC-UHFFFAOYSA-N
- InChI
- InChI=1S/C12H22O5/c13-11(7-3-1-4-8-11)16-17-12(15-14)9-5-2-6-10-12/h13-14H,1-10H2
- SMILES (canonical and isomeric)
- C1CCC(CC1)(O)OOC2(CCCCC2)OO
Synonyms
- Perhexa P
- 1-Hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide
- Cyclohexanone, peroxide
- 1-Hydroperoxycyclohexyl-1-hydroxycyclohexyl peroxide
- 1-Hydroxy-1'-hydroperoxydicyclohexyl peroxide
- Cyclohexanol, 1-((1-hydroperoxycyclohexyl)dioxy)-
- Peroxide, 1-hydroperoxycyclohexyl 1-hydroxycyclohexyl
- Cyclohexanol, 1-[(1-hydroperoxycyclohexyl)dioxy]-
- 4-07-00-00020 (Beilstein Handbook Reference)
- Cycloneox LE
- Cycloneox LNC
- Cycloneox BT 50
- Cycloneox LE 50
- 1Hydroxy1`hydroperoxydicyclohexyl peroxide
- 1-hydroxy-1-hydroperoxydicyclohexyl peroxide
- Cyclohexanol, 1((1hydroperoxycyclohexyl)dioxy)
- 1Hydroperoxycyclohexyl1hydroxycyclohexyl peroxide
- 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol
- 1-((1-hydroperoxycyclohexyl)peroxy)cyclohexan-1-ol
- 1-[(1-hydroperoxycyclohexyl)peroxy]cyclohexan-1-ol
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Grayish pasteexp.Measured value |
|---|---|
| Melting point | 76 to 77exp.Measured value |
| Density | 1.05 at 68 °F - Denser than water, will sinkexp.Measured value |
| Flash point | 157.2 °Cexp.Measured value |
| Autoignition temperature | 402.8 °Cexp.Measured value |
| Solubility | OFF-WHITE THICK PASTE, INSOL IN WATER, SOL IN COMMON ORG SOLVENTS /PASTE WITH DIBUTYL PHTHALATE/exp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 246.30 g/molcalc.Computed value |
|---|---|
| Exact mass | 246.1467 Dacalc.Computed value |
| LogP (octanol/water) | 2.74calc.Computed value |
| Topological polar surface area | 68.15 Ųcalc.Computed value |
| Hydrogen bond donors | 2calc.Computed value |
| Hydrogen bond acceptors | 5calc.Computed value |
| Rotatable bonds | 4calc.Computed value |
| Heavy atoms | 17calc.Computed value |
| Rings | 2calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Murcko scaffold
The ring system that remains when every side chain is removed
C1CCC(OOC2CCCCC2)CC1
2 rings, 14 atoms, the Dicyclohexyl peroxide ring system.
10 other chemicals share this scaffoldSafety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H240Heating may cause an explosion.
- H302Harmful if swallowed.
- H314Causes severe skin burns and eye damage.
Precautionary statements (24)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P234Keep only in original packaging.
- P235Keep cool.
- P240Ground and bond container and receiving equipment.
- P260Do not breathe dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P317If swallowed: Get medical help.
- P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
- P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316Get emergency medical help immediately.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P330Rinse mouth.
- P363Wash contaminated clothing before reuse.
- P370 + P372 + P380 + P373In case of fire: Explosion risk. Evacuate area. Do not fight fire when fire reaches explosives.
- P403Store in a well-ventilated place.
- P405Store locked up.
- P410Protect from sunlight.
- P411Store at temperatures not exceeding the specified limit.
- P420Store separately.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 3105
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidCyclohexanone peroxide suppliers
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- China, ShanghaiUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- China, TianjinUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- TaiwanUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- JapanUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- Turkey, TurkeyUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- United States, Elyria ManufacturerUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
- China, ZiboUnclaimed profileCyclohexanone peroxideGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
7 suppliers in 5 countries
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Cyclohexanone peroxide price
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Uses and applications
What the substance is used for, by industry and function
As a catalyst for hardening of certain fiberglass resins.
Principally as a free radical polymerization initiator.
Powerful oxidizer.
Industrial uses: Polymerization promoter.
Industries and functions
Functional uses
- Chemical reaction regulator
- Hardener
How it is made
Controlled reaction of cyclohexanone and hydrogen peroxide
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 617-010-00-1[4]
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Cyclohexanone peroxide is traded under.
Alcohol peroxides, ether peroxides, acetal and hemiacetal peroxides, ketone peroxides…
- China46.5%
- Germany16.2%
- United States10.1%
- United States11.4%
- Germany8.4%
- South Korea7.3%
The HS code shown for Cyclohexanone peroxide is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Cyclohexanone peroxide, based on the data on this page
What is Cyclohexanone peroxide?
What is the CAS number of Cyclohexanone peroxide?
What is the molecular formula and weight of Cyclohexanone peroxide?
What is Cyclohexanone peroxide used for?
Is Cyclohexanone peroxide hazardous?
What is the HS code of Cyclohexanone peroxide?
Where can I buy Cyclohexanone peroxide?
What is the price of Cyclohexanone peroxide?
Guides for buyers
Practical guides that help when you source, ship or handle Cyclohexanone peroxide
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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