Phenol safety data

GHS hazards, precautions, first aid, handling and transport for Phenol. A classification summary, not a safety data sheet.

CAS 108-95-2Formula C₆H₆O

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

GHS classification

Pictograms, signal word and hazard classes of the GHS classification

Corrosive

Acute toxicity (severe)

Serious health hazard

Signal word

Danger

NFPA 704 rating
health, fire, reactivity

Hazard classes and categories

Acute Tox. 3 (oral)
Acute Tox. 3 (dermal)
Skin Corr. 1
Acute Tox. 3 (inhalation)
Muta. 2
STOT RE 2

Hazard statements

H codes grouped by type. Percentages show the share of classification notifications that report the statement

Health hazards

H301Toxic if swallowed.
H311Toxic in contact with skin.
H314Causes severe skin burns and eye damage.
H331Toxic if inhaled.
H341Suspected of causing genetic defects.
H373May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P codes for prevention, response, storage and disposal

Prevention

P203Obtain, read and follow all safety instructions before use.
P260Do not breathe dust, fume, gas, mist, vapours or spray.
P261Avoid breathing dust, fume, gas, mist, vapours or spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash skin thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves, protective clothing, eye protection and face protection.

Response

P301 + P316If swallowed: Get emergency medical help immediately.
P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
P302 + P352If on skin: Wash with plenty of water.
P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P316Get emergency medical help immediately.
P318If exposed or concerned, get medical advice.
P319Get medical help if you feel unwell.
P321Specific treatment (see supplemental first aid instructions on the label).
P330Rinse mouth.
P361 + P364Take off immediately all contaminated clothing. And wash it before reuse.
P363Wash contaminated clothing before reuse.

Storage

P403 + P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.

Disposal

P501Dispose of contents and container in accordance with local regulations.

First aid

General first aid measures. Get medical advice if you feel unwell

If inhaled

IMMEDIATELY leave the contaminated area, take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used, if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

Skin contact

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.

Eye contact

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

If swallowed

DO NOT INDUCE VOMITING. Phenols are very toxic poisons AND corrosive and irritating, so that inducing vomiting may make medical problems worse. IMMEDIATELY call a hospital or poison control center and locate activated charcoal, egg whites, or milk in case the medical advisor recommends administering one of them. If advice from a physician is not readily available and the victim is conscious and not convulsing, give the victim a glass of activated charcoal slurry in water or, if this is not available, a glass of milk, or beaten egg whites and IMMEDIATELY transport victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, assure that the victim's airway…

Handling, storage and disposal

Summaries only, follow the supplier SDS for your grade

Safe handling

Fire: NO open flames. NO contact with strong oxidizing agents. Above 79 °C use a closed system and ventilation.

General: AVOID ALL CONTACT! FIRST AID: USE PERSONAL PROTECTION. IN ALL CASES CONSULT A DOCTOR!

Inhalation: Avoid inhalation of dust and mist. Use ventilation, local exhaust or breathing protection.

Skin: Protective gloves. Protective clothing.

Eyes: Wear face shield or eye protection in combination with breathing protection.

Ingestion: Do not eat, drink, or smoke during work. Wash hands before eating.

Storage

Provision to contain effluent from fire extinguishing. Separated from strong oxidants and food and feedstuffs. Dry. Well closed. Store only in original container. Keep in a well-ventilated room. Store in an area without drain or sewer access.

Disposal

Incineration is the recommended method of disposal. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner or scrubber. Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number U188, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.

Exposure limits and toxicity

Occupational exposure limits and toxicity data

OSHA PEL, 8-hour TWA: 5 ppm (19mg/m³)
NIOSH REL, TWA: 5 ppm (19 mg/m³)
NIOSH REL, ceiling: 15.6 ppm (60 mg/m³) [15 minutes]
ACGIH TLV, 8-hour TWA: 5 ppm
IDLH: 250 ppm

Short-term exposure: The substance and the vapour are corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest. The substance may cause effects on the central nervous system, heart and kidneys. This may result in convulsions, coma, cardiac disorders, respiratory failure and collapse. The effects may be delayed. Medical observation is indicated. Exposure could cause death. Long-term exposure: The substance may have effects on the liver, kidneys and nervous system.

Transport information

UN dangerous goods classification for road, sea and air

UN number: UN 2312
Transport hazard class: 6.1
Packing group: II

Shipping rules depend on mode, quantity and packaging. Confirm the classification with the supplier SDS and your freight forwarder.

Supplier safety data sheets

SDS documents uploaded by suppliers who list this chemical

No supplier has uploaded an SDS for Phenol yet. Suppliers usually send one with their quote. Request quotes

Safety questions

Quick answers about handling Phenol safely

Is Phenol hazardous?

Phenol carries the GHS signal word "Danger". Main hazards: toxic if swallowed, toxic in contact with skin, causes severe skin burns and eye damage. This summary is not an SDS, always read the supplier safety data sheet.

Which GHS pictograms apply to Phenol?

The GHS classification of Phenol shows 3 pictograms: GHS05 (corrosive), GHS06 (acute toxicity (severe)), GHS08 (serious health hazard).

What is the UN number of Phenol?

Phenol is transported under UN 2312, hazard class 6.1, packing group II. Check the supplier SDS and the current ADR, IMDG or IATA rules before shipping.

How should Phenol be stored?

Where can I get the SDS for Phenol?

Ask the supplier for the safety data sheet of the exact grade you buy. Suppliers on CompoundList can attach their SDS to listings and send it with a quote. This page is a GHS classification summary, not an SDS.

GHS classification summary, not an SDS. Always check the supplier's SDS. Last updated 7 Oct 2026. Report an error

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