CompoundList

1,1-Dichloroethane

Also known as Ethylidene chloride, Ethane, 1,1-dichloro-, Ethylidene dichloride

1,1-Dichloroethane chemical structure, C2H4Cl2, CAS 75-34-3
2D chemical structure

Key facts

What buyers check first

Appearance
Colorless, oily liquid
Melting point
-96.9 °C
Boiling point
57.4 °C
Density
Relative density (water = 1): 1.2
Flash point
-10 °C
HS code
290319
Category
Chlorinated and fluorinated solvents
UN number
UN 2362
Illustrative photo, 200 litre blue HDPE drums of liquid in a warehouse
Typical packagingIllustrative packaging image, not the actual product

What is 1,1-Dichloroethane?

Plain description, key identifiers and synonyms

1,1-Dichloroethane is an organochlorine compound.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
1,1-dichloroethane
CAS number
75-34-3 CAS number cross-checkedOther or deprecated CAS: 1300-21-6, 40202-09-3
EC numbers
200-863-5, 215-077-8
Molecular formula
C2H4Cl2
UNII
0S989LNA44
MDL number
MFCD00013673
InChIKey
SCYULBFZEHDVBN-UHFFFAOYSA-N
InChI
InChI=1S/C2H4Cl2/c1-2(3)4/h2H,1H3
SMILES (canonical and isomeric)
CC(Cl)Cl

Synonyms

  • Ethylidene chloride
  • Ethane, 1,1-dichloro-
  • Ethylidene dichloride
  • 1,1-Dichlorethane
  • Dichloromethylmethane
  • Aethylidenchlorid
  • 1,1-Dicloroetano
  • 1,1-Dichloraethan
  • Cloruro di etilidene
  • 1,1-Dichloorethaan
  • 1,1-Ethylidene dichloride
  • RCRA waste number U076
  • Chlorure D'ethylidene
  • Dichloroethane, 1,1-
  • alpha,alpha-Dichloroethane
  • Asymmetrical dichloroethane
  • HCC 150A
  • Dichloroethane
  • 1,1-Dichloroethane-d4
  • Ethane, dichloro- (8CI,9CI)
  • 1,1-Dichloroethane (stabilized with nitromethane)
  • 1,1-Dichloroethane (Stabilized with Nitromethane, ~0.5%) (>90%)
  • 1,1-Dichloroethane, analytical standard
  • RCRA waste no. U076
  • dichioroethane
Show all 32 synonyms
  • dichlorethane
  • dichloroetane
  • dichloroethan
  • dichloro ethane
  • dichloro-ethane
  • 1,1 dichloroethane
  • 2,2-dichloroethane

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
Colorless, oily liquidexp.
Odour
Aromatic ethereal odorexp.
Taste
As of chloroformexp.
Melting point
-96.9 °Cexp.
Boiling point
57.4 °Cexp.
Density
Relative density (water = 1): 1.2exp.
Flash point
-10 °Cexp.
Autoignition temperature
458 °Cexp.
Solubility
In water, 5,040 mg/L at 25 °Cexp.
Vapour pressure
2.27 × 10⁺² mm Hg at 25 °Cexp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
98.96 g/molcalc.
Exact mass
97.969 Dacalc.
LogP (octanol/water)
1.81calc.
Topological polar surface area
0 Ųcalc.
Hydrogen bond donors
0calc.
Hydrogen bond acceptors
0calc.
Rotatable bonds
0calc.
Heavy atoms
4calc.
Rings
0calc.
Aromatic rings
0calc.
Fraction sp3 carbons
1calc.
Formal charge
0calc.
Stereocentres
0calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Danger
GHS02: Flammable
Flammable
GHS07: Harmful or irritant
Harmful or irritant
310NFPA 704 rating

Hazard statements

  • H225Highly flammable liquid and vapour.
  • H302Harmful if swallowed.
  • H319Causes serious eye irritation.
  • H335May cause respiratory irritation.
  • H412Harmful to aquatic life with long lasting effects.
Precautionary statements (25)
  • P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P233Keep container tightly closed.
  • P240Ground and bond container and receiving equipment.
  • P241Use explosion-proof electrical, ventilating and lighting equipment.
  • P242Use non-sparking tools.
  • P243Take action to prevent static discharges.
  • P261Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264Wash skin thoroughly after handling.
  • P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
  • P270Do not eat, drink or smoke when using this product.
  • P271Use only outdoors or in a well-ventilated area.
  • P273Avoid release to the environment.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.
  • P301 + P317If swallowed: Get medical help.
  • P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
  • P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P319Get medical help if you feel unwell.
  • P330Rinse mouth.
  • P337 + P317If eye irritation persists: Get medical help.
  • P370 + P378In case of fire: Use appropriate media to extinguish.
  • P403 + P233Store in a well-ventilated place. Keep container tightly closed.
  • P403 + P235Store in a well-ventilated place. Keep cool.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 2362
Transport hazard class
3
Packing group
II

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

1,1-Dichloroethane suppliers

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Where suppliers are based

16 suppliers in 2 countries

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1,1-Dichloroethane price

Indicative price range per kg from live supplier offers

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Uses and applications

What the substance is used for, by industry and function

Reagent and chemical intermediate. Solvent for paint, varnishes, degreaser.

1,1-Dichlorethane is used as a chemical intermediate and grain fumigant and has limited use as a solvent for plastics, oils, and fats. It was formerly used as an anesthetic but it is of no importance in this field today.

Used in the manufacture of high vacuum rubber and silicone grease.

Primarily used as a feedstock for the production of 1,1,1-trichloroethane.

Most commonly used in the production of vinyl chloride monomer (1,2-dichloroethane).

Industrial uses: Intermediate.

Use classes: Volatile organic compounds.

Functional uses

  • Solvent

How it is made

Prepared by the action of PCl5 (phosphorus pentachloride) on acetaldehyde.

1,1-Dichloroethane may ... be obtained by ethane or chloroethane chlorination. This chlorination can be carried out as thermal chlorination, photochlorination, or oxychlorination. These processes, however, are impaired by a lack of selectivity.

1,1-Dichloroethane can be produced from acetylene by adding 2 mol of hydrogen chloride. For the first reaction sequence, i.e., the formation of vinyl chloride, mercury catalyst is typically used, although other nonmercuric catalysts are claimed in the literature.

Regulatory status

Inventories, regulations and trade controls that list this substance

Europe

  • EU harmonised classification (CLP Annex VI)
    Index no: 602-011-00-1

United States

  • TSCA inventory (USA)
    Status: Active in US commerce, Regulatory flags: Section 4 test rule or order

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code 1,1-Dichloroethane is traded under.

HS 2903.19Indicative HS code

Saturated chlorinated derivatives of acyclic hydrocarbons, other

World exports in 2024
$81.2M
−13.3% vs 2023, imports $81.1M
2019 to 2024
Top exporters
  1. China32.6%
  2. Germany25.6%
  3. Brazil18.2%
Top importers
  1. United States35.7%
  2. South Korea7.6%
  3. India * partner reported6.7%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for 1,1-Dichloroethane is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about 1,1-Dichloroethane, based on the data on this page

What is 1,1-Dichloroethane?

1,1-Dichloroethane is an organochlorine compound.

What is the CAS number of 1,1-Dichloroethane?

The CAS registry number of 1,1-Dichloroethane is 75-34-3. Other or deprecated CAS numbers: 1300-21-6, 40202-09-3.

What is the molecular formula and weight of 1,1-Dichloroethane?

The molecular formula of 1,1-Dichloroethane is C2H4Cl2 and its molar mass is 98.96 g/mol.

What is 1,1-Dichloroethane used for?

Reagent and chemical intermediate. Solvent for paint, varnishes, degreaser. 1,1-Dichlorethane is used as a chemical intermediate and grain fumigant and has limited use as a solvent for plastics, oils, and fats. It was formerly used as an anesthetic but it is of no importance in this field today.

Is 1,1-Dichloroethane hazardous?

1,1-Dichloroethane carries the GHS signal word "Danger". Main hazards: highly flammable liquid and vapour, harmful if swallowed, causes serious eye irritation. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of 1,1-Dichloroethane?

1,1-Dichloroethane is usually classified under HS code 290319 (Saturated chlorinated derivatives of acyclic hydrocarbons, other). This is indicative, confirm it with your customs broker before shipping.

Where can I buy 1,1-Dichloroethane?

CompoundList lists 16 suppliers of 1,1-Dichloroethane in China and United States. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

What is the price of 1,1-Dichloroethane?

Suppliers quote 1,1-Dichloroethane on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle 1,1-Dichloroethane

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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