1,1-Dichloroethane
Also known as Ethylidene chloride, Ethane, 1,1-dichloro-, Ethylidene dichloride
Key facts
What buyers check first
- Appearance
- Colorless, oily liquid
- Melting point
- -96.9 °C
- Boiling point
- 57.4 °C
- Density
- Relative density (water = 1): 1.2
- Flash point
- -10 °C
- HS code
- 290319
- Category
- Chlorinated and fluorinated solvents
- UN number
- UN 2362

What is 1,1-Dichloroethane?
Plain description, key identifiers and synonyms
1,1-Dichloroethane is an organochlorine compound.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- 1,1-dichloroethane
- CAS number
- 75-34-3 CAS number cross-checkedOther or deprecated CAS: 1300-21-6, 40202-09-3
- EC numbers
- 200-863-5, 215-077-8
- Molecular formula
- C2H4Cl2
- UNII
- 0S989LNA44
- MDL number
- MFCD00013673
- InChIKey
- SCYULBFZEHDVBN-UHFFFAOYSA-N
- InChI
- InChI=1S/C2H4Cl2/c1-2(3)4/h2H,1H3
- SMILES (canonical and isomeric)
- CC(Cl)Cl
Synonyms
- Ethylidene chloride
- Ethane, 1,1-dichloro-
- Ethylidene dichloride
- 1,1-Dichlorethane
- Dichloromethylmethane
- Aethylidenchlorid
- 1,1-Dicloroetano
- 1,1-Dichloraethan
- Cloruro di etilidene
- 1,1-Dichloorethaan
- 1,1-Ethylidene dichloride
- RCRA waste number U076
- Chlorure D'ethylidene
- Dichloroethane, 1,1-
- alpha,alpha-Dichloroethane
- Asymmetrical dichloroethane
- HCC 150A
- Dichloroethane
- 1,1-Dichloroethane-d4
- Ethane, dichloro- (8CI,9CI)
- 1,1-Dichloroethane (stabilized with nitromethane)
- 1,1-Dichloroethane (Stabilized with Nitromethane, ~0.5%) (>90%)
- 1,1-Dichloroethane, analytical standard
- RCRA waste no. U076
- dichioroethane
Show all 32 synonymsShow fewer synonyms
- dichlorethane
- dichloroetane
- dichloroethan
- dichloro ethane
- dichloro-ethane
- 1,1 dichloroethane
- 2,2-dichloroethane
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless, oily liquidexp.Measured value |
|---|---|
| Odour | Aromatic ethereal odorexp.Measured value |
| Taste | As of chloroformexp.Measured value |
| Melting point | -96.9 °Cexp.Measured value |
| Boiling point | 57.4 °Cexp.Measured value |
| Density | Relative density (water = 1): 1.2exp.Measured value |
| Flash point | -10 °Cexp.Measured value |
| Autoignition temperature | 458 °Cexp.Measured value |
| Solubility | In water, 5,040 mg/L at 25 °Cexp.Measured value |
| Vapour pressure | 2.27 × 10⁺² mm Hg at 25 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 98.96 g/molcalc.Computed value |
|---|---|
| Exact mass | 97.969 Dacalc.Computed value |
| LogP (octanol/water) | 1.81calc.Computed value |
| Topological polar surface area | 0 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 0calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 4calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H225Highly flammable liquid and vapour.
- H302Harmful if swallowed.
- H319Causes serious eye irritation.
- H335May cause respiratory irritation.
- H412Harmful to aquatic life with long lasting effects.
Precautionary statements (25)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P233Keep container tightly closed.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P242Use non-sparking tools.
- P243Take action to prevent static discharges.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P273Avoid release to the environment.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P317If swallowed: Get medical help.
- P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P319Get medical help if you feel unwell.
- P330Rinse mouth.
- P337 + P317If eye irritation persists: Get medical help.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P403 + P235Store in a well-ventilated place. Keep cool.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 2362
- Transport hazard class
- 3
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aid1,1-Dichloroethane suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- ChinaUnclaimed profileDichloroethaneGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileEthylidene chlorideGrade, purity and minimum order on requestPrice on request
- China ManufacturerUnclaimed profile1,1-DichloroethaneGrade, purity and minimum order on requestPrice on request
- China, Shanghai ManufacturerUnclaimed profile1,1-DichloroethaneGrade, purity and minimum order on requestPrice on request
- China, NanjingUnclaimed profileDichloroethaneGrade, purity and minimum order on requestPrice on request
- China, Zibo ManufacturerUnclaimed profileEthylidene chlorideGrade, purity and minimum order on requestPrice on request
- China, ChangzhouUnclaimed profileEthylidene chlorideGrade, purity and minimum order on requestPrice on request
- Price on request
- United States, Houston ManufacturerUnclaimed profile1,1-DichloroethaneGrade, purity and minimum order on requestPrice on request
- United States, Houston ManufacturerUnclaimed profile1,1-DichloroethaneGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
16 suppliers in 2 countries
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1,1-Dichloroethane price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
Reagent and chemical intermediate. Solvent for paint, varnishes, degreaser.
1,1-Dichlorethane is used as a chemical intermediate and grain fumigant and has limited use as a solvent for plastics, oils, and fats. It was formerly used as an anesthetic but it is of no importance in this field today.
Used in the manufacture of high vacuum rubber and silicone grease.
Primarily used as a feedstock for the production of 1,1,1-trichloroethane.
Most commonly used in the production of vinyl chloride monomer (1,2-dichloroethane).
Industrial uses: Intermediate.
Use classes: Volatile organic compounds.
Functional uses
- Solvent
How it is made
Prepared by the action of PCl5 (phosphorus pentachloride) on acetaldehyde.
1,1-Dichloroethane may ... be obtained by ethane or chloroethane chlorination. This chlorination can be carried out as thermal chlorination, photochlorination, or oxychlorination. These processes, however, are impaired by a lack of selectivity.
1,1-Dichloroethane can be produced from acetylene by adding 2 mol of hydrogen chloride. For the first reaction sequence, i.e., the formation of vinyl chloride, mercury catalyst is typically used, although other nonmercuric catalysts are claimed in the literature.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 602-011-00-1
United States
- TSCA inventory (USA)Status: Active in US commerce, Regulatory flags: Section 4 test rule or order
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code 1,1-Dichloroethane is traded under.
Saturated chlorinated derivatives of acyclic hydrocarbons, other
- United States35.7%
- South Korea7.6%
- India * partner reported6.7%
* Partner reported figures, a lower bound.
The HS code shown for 1,1-Dichloroethane is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about 1,1-Dichloroethane, based on the data on this page
What is 1,1-Dichloroethane?
What is the CAS number of 1,1-Dichloroethane?
What is the molecular formula and weight of 1,1-Dichloroethane?
What is 1,1-Dichloroethane used for?
Is 1,1-Dichloroethane hazardous?
What is the HS code of 1,1-Dichloroethane?
Where can I buy 1,1-Dichloroethane?
What is the price of 1,1-Dichloroethane?
Guides for buyers
Practical guides that help when you source, ship or handle 1,1-Dichloroethane
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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