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2,3,4,6-Tetrachlorophenol chemical structure, C6H2Cl4O, CAS 58-90-2
2D chemical structure

Key facts

What buyers check first

Appearance
Needles from ligroin, acetic acid
Melting point
70 °C
Boiling point
64 °C
Density
1.8 g/cm³
Flash point
100 °C
HS code
290819
Category
Fungicides
UN number
UN 2020
Illustrative photo, a shrink wrapped pallet of kraft paper sacks in a chemical plant
Typical packagingIllustrative packaging image, not the actual product

What is 2,3,4,6-Tetrachlorophenol?

Plain description, key identifiers and synonyms

2,3,4,6-tetrachlorophenol is a tetrachlorophenol in which the chlorines are located at positions 2, 3, 4, and 6. It has a role as a xenobiotic metabolite.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
2,3,4,6-tetrachlorophenol
CAS number
58-90-2 CAS number cross-checked
EC number
200-402-8
Molecular formula
C6H2Cl4O
UNII
2442S914FX
MDL number
MFCD00019979
InChIKey
VGVRPFIJEJYOFN-UHFFFAOYSA-N
InChI
InChI=1S/C6H2Cl4O/c7-2-1-3(8)6(11)5(10)4(2)9/h1,11H
SMILES (canonical and isomeric)
C1=C(C(=C(C(=C1Cl)Cl)Cl)O)Cl

Synonyms

  • Dowicide 6
  • 2,4,5,6-Tetrachlorophenol
  • Phenol, 2,3,4,6-tetrachloro-
  • 1-Hydroxy-2,3,4,6-tetrachlorobenzene
  • 2,3,4,6-Tetrachlorophenate
  • 2,3,4,6-tetrakis(chloranyl)phenol
  • Chlorophenols
  • 2,4,5,6-Tetrachlorophenol (contains 10% pentachlorophenol)
  • RCRA waste number U212
  • RCRA waste no. U212
  • KY 5
  • 2,3,4,6-TeCP
  • 2,4,6-Tetrachlorophenol
  • Phenol,3,4,6-tetrachloro-
  • 4-06-00-01021 (Beilstein Handbook Reference)
  • 1-Hydroxy-2,4,6-tetrachlorobenzene
  • 2,3,4,6-Tetrachlorophenol Standard
  • 2,3,4,6-Tetrachlorophenol,
  • 2,3,4,6-Tetrachlorophenol, analytical standard
  • 2,3,4,6-Tetrachlorophenol 10 microg/mL in Cyclohexane
  • 2,3,4,6-Tetrachlorophenol 100 microg/mL in Methanol
  • 2,3,4,6-Tetrachlorophenol 1000 microg/mL in Methanol
  • 2,3,4,6-tetrachlorophenol Solution in Methanol, 1000ug/mL
  • 2,3,4,6-Tetrachlorophenol, vial of 1 g, analytical standard
  • 2,4,5,6-Tetrachlorophenol (contains 10per cent pentachlorophenol)

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
Needles from ligroin, acetic acidexp.
Odour
STRONG ODORexp.
Taste
Taste threshold conc: 0.001 mg/lexp.
Melting point
70 °Cexp.
Boiling point
64 °Cexp.
Density
1.8 g/cm³exp.
Flash point
100 °Cexp.
Solubility
SLIGHTLY SOL IN HOT WATER, VERY SOL IN SODIUM HYDROXIDE, SOL IN HOT ACETIC ACID.exp.
Vapour pressure
4.23 × 10⁻³ mm Hg at 25 °Cexp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
231.89 g/molcalc.
Exact mass
229.886 Dacalc.
LogP (octanol/water)
4.01calc.
Topological polar surface area
20.23 Ųcalc.
Hydrogen bond donors
1calc.
Hydrogen bond acceptors
1calc.
Rotatable bonds
0calc.
Heavy atoms
11calc.
Rings
1calc.
Aromatic rings
1calc.
Fraction sp3 carbons
0calc.
Formal charge
0calc.
Stereocentres
0calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Murcko scaffold

The ring system that remains when every side chain is removed

Murcko scaffold of this chemical, c1ccccc1

c1ccccc1

1 ring, 6 atoms, the Benzene ring system.

485,677 other chemicals share this scaffold

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Danger
GHS06: Acute toxicity (severe)
Acute toxicity (severe)
GHS09: Hazardous to the environment
Hazardous to the environment

Hazard statements

  • H301Toxic if swallowed.
  • H315Causes skin irritation.
  • H319Causes serious eye irritation.
  • H400Very toxic to aquatic life.
  • H410Very toxic to aquatic life with long lasting effects.
Precautionary statements (16)
  • P264Wash skin thoroughly after handling.
  • P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
  • P270Do not eat, drink or smoke when using this product.
  • P273Avoid release to the environment.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.
  • P301 + P316If swallowed: Get emergency medical help immediately.
  • P302 + P352If on skin: Wash with plenty of water.
  • P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P321Specific treatment (see supplemental first aid instructions on the label).
  • P330Rinse mouth.
  • P332 + P317If skin irritation occurs: Get medical help.
  • P337 + P317If eye irritation persists: Get medical help.
  • P362 + P364Take off contaminated clothing. And wash it before reuse.
  • P391Collect spillage.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 2020
Transport hazard class
6.1
Packing group
III

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

2,3,4,6-Tetrachlorophenol suppliers

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2,3,4,6-Tetrachlorophenol price

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Uses and applications

What the substance is used for, by industry and function

Pesticide (former).

Slimicide for paper mills (former).

Preservative, component in pentachlorophenol wood preservative (former).

Fungicide (former).

Roles

  • metabolite
  • xenobiotic metabolite

How it is made

Chlorination of phenol in the presence of potassium tellurate as a catalyst, followed by separation of isomeric mixt, by product from production of pentachlorophenol by chlorination of phenol.

The tri- and tetrachlorophenols produced by direct chlorination of phenol have essentially similar chlorophenol contaminants, varying in concentrations with source and batch. (Tetrachlorophenols)

Regulatory status

Inventories, regulations and trade controls that list this substance

Europe

  • EU harmonised classification (CLP Annex VI)
    Index no: 604-013-00-8

United States

  • TSCA inventory (USA)
    Status: Active in US commerce

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code 2,3,4,6-Tetrachlorophenol is traded under.

HS 2908.19Indicative HS code

Derivatives containing only halogen substituents and their salts, other

World exports in 2024
$452M
−8.2% vs 2023, imports $435M
2019 to 2024
Top exporters
  1. Jordan * partner reported36.5%
  2. Israel29.6%
  3. China6.5%
Top importers
  1. China58.6%
  2. South Korea10.3%
  3. United States5.5%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for 2,3,4,6-Tetrachlorophenol is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about 2,3,4,6-Tetrachlorophenol, based on the data on this page

What is 2,3,4,6-Tetrachlorophenol?

2,3,4,6-tetrachlorophenol is a tetrachlorophenol in which the chlorines are located at positions 2, 3, 4, and 6. It has a role as a xenobiotic metabolite.

What is the CAS number of 2,3,4,6-Tetrachlorophenol?

The CAS registry number of 2,3,4,6-Tetrachlorophenol is 58-90-2.

What is the molecular formula and weight of 2,3,4,6-Tetrachlorophenol?

The molecular formula of 2,3,4,6-Tetrachlorophenol is C6H2Cl4O and its molar mass is 231.89 g/mol.

What is 2,3,4,6-Tetrachlorophenol used for?

Pesticide (former). Slimicide for paper mills (former). Preservative, component in pentachlorophenol wood preservative (former). Fungicide (former).

Is 2,3,4,6-Tetrachlorophenol hazardous?

2,3,4,6-Tetrachlorophenol carries the GHS signal word "Danger". Main hazards: toxic if swallowed, causes skin irritation, causes serious eye irritation. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of 2,3,4,6-Tetrachlorophenol?

2,3,4,6-Tetrachlorophenol is usually classified under HS code 290819 (Derivatives containing only halogen substituents and their salts, other). This is indicative, confirm it with your customs broker before shipping.

Where can I buy 2,3,4,6-Tetrachlorophenol?

CompoundList lists 14 suppliers of 2,3,4,6-Tetrachlorophenol in United States, China, Canada, Hong Kong and 1 more. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

What is the price of 2,3,4,6-Tetrachlorophenol?

Suppliers quote 2,3,4,6-Tetrachlorophenol on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle 2,3,4,6-Tetrachlorophenol

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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