3-Aminophenol
Also known as m-Aminophenol, 3-Hydroxyaniline, m-Hydroxyaniline
Key facts
What buyers check first
- Appearance
- White prisms from toluene or water
- Melting point
- 123 ยฐC
- Boiling point
- 284 ยฐC
- Density
- 1.195 g/cmยณ
- Solubility
- Freely soluble in amyl alcohol and hot water, soluble in 40 parts cold water, very slighโฆ
- HS code
- 292229
- Category
- Dye intermediates
- UN number
- UN 2512

What is 3-Aminophenol?
Plain description, key identifiers and synonyms
3-aminophenol is an aminophenol that is one of three amino derivatives of phenol which has the single amino substituent located meta to the phenolic -OH group.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- 3-aminophenol
- CAS number
- 591-27-5 CAS number cross-checkedOther or deprecated CAS: 52984-90-4
- EC number
- 209-711-2
- Molecular formula
- C6H7NO
- UNII
- L3WTS6QT82
- MDL number
- MFCD00007786
- INCI name
- M-AMINOPHENOL
- InChIKey
- CWLKGDAVCFYWJK-UHFFFAOYSA-N
- InChI
- InChI=1S/C6H7NO/c7-5-2-1-3-6(8)4-5/h1-4,8H,7H2
- SMILES (canonical and isomeric)
- C1=CC(=CC(=C1)O)N
Synonyms
- m-Aminophenol
- 3-Hydroxyaniline
- m-Hydroxyaniline
- Phenol, 3-amino-
- 1-Amino-3-hydroxybenzene
- Fouramine EG
- Futramine EG
- Fourrine EG
- m-Hydroxyaminobenzene
- Pelagol EG
- Tertral EG
- Furro EG
- Renal EG
- Ursol EG
- 3-Amino-1-hydroxybenzene
- Fourrine 65
- Zoba EG
- Nako TEG
- m-Hydroxyphenylamine
- Phenol, m-amino-
- BASF ursol EG
- m-Aminofenol
- C.I. Oxidation Base 7
- CI Oxidation Base 7
- C.I. 76545
Show all 37 synonymsShow fewer synonyms
- RODOL EG
- meta-aminophenol
- CI 76545
- Covastyle map
- Colorex map
- Jarocol map
- Oristar aph3
- 3-amino-phenol
- 3-hydroxybenzenamine
- Mesalazine EP Impurity B
- aniline, 3-hydroxy-
- 3-azaniumylphenolate
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | White prisms from toluene or waterexp.Measured value |
|---|---|
| Melting point | 123 ยฐCexp.Measured value |
| Boiling point | 284 ยฐCexp.Measured value |
| Density | 1.195 g/cmยณexp.Measured value |
| Solubility | Freely soluble in amyl alcohol and hot water, soluble in 40 parts cold water, very slightly soluble in petroleum etherexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 109.13 g/molcalc.Computed value |
|---|---|
| Exact mass | 109.0528 Dacalc.Computed value |
| LogP (octanol/water) | 0.97calc.Computed value |
| Topological polar surface area | 46.25 ร
ยฒcalc.Computed value |
| Hydrogen bond donors | 2calc.Computed value |
| Hydrogen bond acceptors | 2calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 8calc.Computed value |
| Rings | 1calc.Computed value |
| Aromatic rings | 1calc.Computed value |
| Fraction sp3 carbons | 0calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Murcko scaffold
The ring system that remains when every side chain is removed
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H302Harmful if swallowed.
- H332Harmful if inhaled.
- H411Toxic to aquatic life with long lasting effects.
Precautionary statements (11)
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P273Avoid release to the environment.
- P301 + P317If swallowed: Get medical help.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P317Get medical help.
- P330Rinse mouth.
- P391Collect spillage.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 2512
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aid3-Aminophenol suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- India, Mumbai ManufacturerUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- India, Ahmedabad ManufacturerUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- China, Shaoxing ManufacturerUnclaimed profileM -AminophenolGrade, purity and minimum order on requestPrice on request
- China, Wuxi ManufacturerUnclaimed profileM-aminophenolGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- China, HangzhouUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- China, CangzhouUnclaimed profilem-AminophenolGrade, purity and minimum order on requestPrice on request
- United Arab Emirates, Dubai ManufacturerUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- India, MumbaiUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
- United StatesUnclaimed profile3-AminophenolGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
75 suppliers in 16 countries
- China31
- India18
- United States12
- Pakistan2
- United Arab Emirates1
- Brazil1
- and 10 more countries
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3-Aminophenol price
Indicative price range per kg from live supplier offers
Suppliers quote this chemical on request. Send one free request and compare quotes side by side.
Uses and applications
What the substance is used for, by industry and function
Dye intermediate, manufacture of p-aminosalicylic acid.
3-Aminophenol has been used as a stabilizer of chlorine-containing thermoplastics, although its principal use is as an intermediate in the production of 4-amino-2-hydroxybenzoic acid...This isomer is also employed as a hair colorant and as a coupler molecule in hair dyes.
Used as a chemical intermediate for the synthesis of: 7-amino-3-phenylcoumarin, p-aminosalicylic acid, desmedipham, flutolanil, formetanate hydrochloride, karbutilate, mepronil, phenmedipham.
Used in hair dyes in japan. Prepn may also be used to color other substances containing keratin.
Industrial uses: Monomers.
Use classes: Cosmetics, Pesticide transformation products.
Industries and functions
Cosmetic ingredient, INCI name M-AMINOPHENOL(hair dyeing)
Functional uses
- Dye
Cosmetic functions
- Hair dyeing
How it is made
3-Aminophenol cannot be obtained easily by reduction. It is made mainly by the reaction of 3-aminobenzenesulfonic acid with sodium hydroxide or by the reaction of resorcinol with ammonia. Substitution of the sulfonic acid group in 3-aminobenzenesulfonic acid is accomplished by caustic soda fusion (5 - 6 hr, 240 - 245 ยฐC). The product is purified by vacuum distillation. Alternatively, resorcinol reacts with ammonia, for example, in the presence of diammonium phosphate and arsenic pentoxide or ammonium sulfite to form 3-aminophenol. The compound also may be made by hydrolysis of 3-aminoaniline
Manufactured by redn of m-nitrophenol
Fusion of m-sulfanilic acid with caustic soda and subsequent extraction of the melt with ether.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 612-127-00-4
Health and food
- EU cosmetic ingredient inventory
- EU Cosmetics Regulation Annex III, restricted in cosmeticsName: M-AMINOPHENOL, M-AMINOPHENOL HCL, M-AMINOPHENOL SULFATE, Ref no: 217, Annex ref: III/217
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code 3-Aminophenol is traded under.
Amino-naphthols and other amino-phenols, other than those containing more than one kindโฆ
- India * partner reported25.8%
- United States14.4%
- South Korea7.6%
* Partner reported figures, a lower bound.
The HS code shown for 3-Aminophenol is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about 3-Aminophenol, based on the data on this page
What is 3-Aminophenol?
What is the CAS number of 3-Aminophenol?
What is the molecular formula and weight of 3-Aminophenol?
What is 3-Aminophenol used for?
Is 3-Aminophenol hazardous?
What is the HS code of 3-Aminophenol?
Where can I buy 3-Aminophenol?
Where can I buy 3-Aminophenol in India?
What is the price of 3-Aminophenol?
Guides for buyers
Practical guides that help when you source, ship or handle 3-Aminophenol
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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