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3-Aminophenol chemical structure, C6H7NO, CAS 591-27-5
2D chemical structure

Key facts

What buyers check first

Appearance
White prisms from toluene or water
Melting point
123 ยฐC
Boiling point
284 ยฐC
Density
1.195 g/cmยณ
Solubility
Freely soluble in amyl alcohol and hot water, soluble in 40 parts cold water, very slighโ€ฆ
HS code
292229
Category
Dye intermediates
UN number
UN 2512
Illustrative photo, colourless crystals in an open fibre drum in a chemical plant
Typical packagingIllustrative packaging image, not the actual product

What is 3-Aminophenol?

Plain description, key identifiers and synonyms

3-aminophenol is an aminophenol that is one of three amino derivatives of phenol which has the single amino substituent located meta to the phenolic -OH group.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
3-aminophenol
CAS number
591-27-5 CAS number cross-checkedOther or deprecated CAS: 52984-90-4
EC number
209-711-2
Molecular formula
C6H7NO
UNII
L3WTS6QT82
MDL number
MFCD00007786
INCI name
M-AMINOPHENOL
InChIKey
CWLKGDAVCFYWJK-UHFFFAOYSA-N
InChI
InChI=1S/C6H7NO/c7-5-2-1-3-6(8)4-5/h1-4,8H,7H2
SMILES (canonical and isomeric)
C1=CC(=CC(=C1)O)N

Synonyms

  • m-Aminophenol
  • 3-Hydroxyaniline
  • m-Hydroxyaniline
  • Phenol, 3-amino-
  • 1-Amino-3-hydroxybenzene
  • Fouramine EG
  • Futramine EG
  • Fourrine EG
  • m-Hydroxyaminobenzene
  • Pelagol EG
  • Tertral EG
  • Furro EG
  • Renal EG
  • Ursol EG
  • 3-Amino-1-hydroxybenzene
  • Fourrine 65
  • Zoba EG
  • Nako TEG
  • m-Hydroxyphenylamine
  • Phenol, m-amino-
  • BASF ursol EG
  • m-Aminofenol
  • C.I. Oxidation Base 7
  • CI Oxidation Base 7
  • C.I. 76545
Show all 37 synonyms
  • RODOL EG
  • meta-aminophenol
  • CI 76545
  • Covastyle map
  • Colorex map
  • Jarocol map
  • Oristar aph3
  • 3-amino-phenol
  • 3-hydroxybenzenamine
  • Mesalazine EP Impurity B
  • aniline, 3-hydroxy-
  • 3-azaniumylphenolate

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
White prisms from toluene or waterexp.
Melting point
123 ยฐCexp.
Boiling point
284 ยฐCexp.
Density
1.195 g/cmยณexp.
Solubility
Freely soluble in amyl alcohol and hot water, soluble in 40 parts cold water, very slightly soluble in petroleum etherexp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
109.13 g/molcalc.
Exact mass
109.0528 Dacalc.
LogP (octanol/water)
0.97calc.
Topological polar surface area
46.25 ร…ยฒcalc.
Hydrogen bond donors
2calc.
Hydrogen bond acceptors
2calc.
Rotatable bonds
0calc.
Heavy atoms
8calc.
Rings
1calc.
Aromatic rings
1calc.
Fraction sp3 carbons
0calc.
Formal charge
0calc.
Stereocentres
0calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Murcko scaffold

The ring system that remains when every side chain is removed

Murcko scaffold of this chemical, c1ccccc1

c1ccccc1

1 ring, 6 atoms, the Benzene ring system.

485,677 other chemicals share this scaffold

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Warning
GHS07: Harmful or irritant
Harmful or irritant
GHS09: Hazardous to the environment
Hazardous to the environment
020NFPA 704 rating

Hazard statements

  • H302Harmful if swallowed.
  • H332Harmful if inhaled.
  • H411Toxic to aquatic life with long lasting effects.
Precautionary statements (11)
  • P261Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P264Wash skin thoroughly after handling.
  • P270Do not eat, drink or smoke when using this product.
  • P271Use only outdoors or in a well-ventilated area.
  • P273Avoid release to the environment.
  • P301 + P317If swallowed: Get medical help.
  • P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • P317Get medical help.
  • P330Rinse mouth.
  • P391Collect spillage.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 2512

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

3-Aminophenol suppliers

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3-Aminophenol price

Indicative price range per kg from live supplier offers

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Uses and applications

What the substance is used for, by industry and function

Dye intermediate, manufacture of p-aminosalicylic acid.

3-Aminophenol has been used as a stabilizer of chlorine-containing thermoplastics, although its principal use is as an intermediate in the production of 4-amino-2-hydroxybenzoic acid...This isomer is also employed as a hair colorant and as a coupler molecule in hair dyes.

Used as a chemical intermediate for the synthesis of: 7-amino-3-phenylcoumarin, p-aminosalicylic acid, desmedipham, flutolanil, formetanate hydrochloride, karbutilate, mepronil, phenmedipham.

Used in hair dyes in japan. Prepn may also be used to color other substances containing keratin.

Industrial uses: Monomers.

Use classes: Cosmetics, Pesticide transformation products.

Cosmetic ingredient, INCI name M-AMINOPHENOL(hair dyeing)

Functional uses

  • Dye

Cosmetic functions

  • Hair dyeing

How it is made

3-Aminophenol cannot be obtained easily by reduction. It is made mainly by the reaction of 3-aminobenzenesulfonic acid with sodium hydroxide or by the reaction of resorcinol with ammonia. Substitution of the sulfonic acid group in 3-aminobenzenesulfonic acid is accomplished by caustic soda fusion (5 - 6 hr, 240 - 245 ยฐC). The product is purified by vacuum distillation. Alternatively, resorcinol reacts with ammonia, for example, in the presence of diammonium phosphate and arsenic pentoxide or ammonium sulfite to form 3-aminophenol. The compound also may be made by hydrolysis of 3-aminoaniline

Manufactured by redn of m-nitrophenol

Fusion of m-sulfanilic acid with caustic soda and subsequent extraction of the melt with ether.

Regulatory status

Inventories, regulations and trade controls that list this substance

Europe

  • EU harmonised classification (CLP Annex VI)
    Index no: 612-127-00-4

Health and food

  • EU cosmetic ingredient inventory
  • EU Cosmetics Regulation Annex III, restricted in cosmetics
    Name: M-AMINOPHENOL, M-AMINOPHENOL HCL, M-AMINOPHENOL SULFATE, Ref no: 217, Annex ref: III/217

United States

  • TSCA inventory (USA)
    Status: Active in US commerce

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code 3-Aminophenol is traded under.

HS 2922.29Indicative HS code

Amino-naphthols and other amino-phenols, other than those containing more than one kindโ€ฆ

World exports in 2024
$467M
โˆ’15.3% vs 2023, imports $454M
2019 to 2024
Top exporters
  1. China63.1%
  2. India * partner reported15.5%
  3. Japan4.0%
Top importers
  1. India * partner reported25.8%
  2. United States14.4%
  3. South Korea7.6%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for 3-Aminophenol is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about 3-Aminophenol, based on the data on this page

What is 3-Aminophenol?

3-aminophenol is an aminophenol that is one of three amino derivatives of phenol which has the single amino substituent located meta to the phenolic -OH group.

What is the CAS number of 3-Aminophenol?

The CAS registry number of 3-Aminophenol is 591-27-5. Other or deprecated CAS numbers: 52984-90-4.

What is the molecular formula and weight of 3-Aminophenol?

The molecular formula of 3-Aminophenol is C6H7NO and its molar mass is 109.13 g/mol.

What is 3-Aminophenol used for?

Dye intermediate, manufacture of p-aminosalicylic acid. 3-Aminophenol has been used as a stabilizer of chlorine-containing thermoplastics, although its principal use is as an intermediate in the production of 4-amino-2-hydroxybenzoic acid...This isomer is also employed as a hair colorant and as a coupler molecule in hโ€ฆ

Is 3-Aminophenol hazardous?

3-Aminophenol carries the GHS signal word "Warning". Main hazards: harmful if swallowed, harmful if inhaled, toxic to aquatic life with long lasting effects. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of 3-Aminophenol?

3-Aminophenol is usually classified under HS code 292229 (Amino-naphthols and other amino-phenols, other than those containing more than one kindโ€ฆ). This is indicative, confirm it with your customs broker before shipping.

Where can I buy 3-Aminophenol?

CompoundList lists 75 suppliers of 3-Aminophenol in China, India, United States, Pakistan and 12 more. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

Where can I buy 3-Aminophenol in India?

18 suppliers in India list 3-Aminophenol on CompoundList. Filter the suppliers list by country and send a request to compare prices, grades and delivery times.

What is the price of 3-Aminophenol?

Suppliers quote 3-Aminophenol on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle 3-Aminophenol

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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