Cyclohexanol
Also known as Cyclohexyl alcohol, 1-Cyclohexanol, Hexahydrophenol
Key facts
What buyers check first
- Appearance
- Colorless needles or viscous liquid
- Melting point
- 25.9 °C
- Boiling point
- 161.8 °C
- Density
- Relative density (water = 1): 0.96
- Flash point
- 62.8 °C
- HS code
- 290612
- Category
- Alcohol and glycol solvents
- UN number
- UN 1986

What is Cyclohexanol?
Plain description, key identifiers and synonyms
Cyclohexanol is an alcohol that consists of cyclohexane bearing a single hydroxy substituent. The parent of the class of cyclohexanols. It has a role as a solvent. It is a member of cyclohexanols and a secondary alcohol.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- cyclohexanol
- CAS number
- 108-93-0 CAS number cross-checked
- EC number
- 203-630-6
- Molecular formula
- C6H12O
- UNII
- 8E7S519M3P
- MDL number
- MFCD00003855
- INCI name
- CYCLOHEXANOL
- InChIKey
- HPXRVTGHNJAIIH-UHFFFAOYSA-N
- InChI
- InChI=1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2
- SMILES (canonical and isomeric)
- C1CCC(CC1)O
Synonyms
- Cyclohexyl alcohol
- 1-Cyclohexanol
- Hexahydrophenol
- Hydrophenol
- Hydroxycyclohexane
- Hexalin
- Adronal
- Hydralin
- Naxol
- Adronol
- Anol
- Cicloesanolo
- Cykloheksanol
- Phenol, hexahydro-
- Cyclohexan-1-ol
- Cyclohexanol-d11
- CXL
- Cyclohexanols
- Hydroxycyclohexane, NSC 403656, NSC 54711, Naxol, Phenol, hexahydro-
- Cylcohexanol
- cyclohexyl-alcohol
- Cyclohexane, hydroxy-
- 4-06-00-00020 (Beilstein Handbook Reference)
- Cyclohexanol, p.a., 99.0%
- Cyclohexanol, analytical standard
Show all 31 synonymsShow fewer synonyms
- Cyclohexanol, ReagentPlus(R), 99%
- Cyclohexanol, puriss., >=99.0% (GC)
- Cyclohexanol, SAJ first grade, >=95.0%
- Cyclohexanol Solution in Methanol, 100ug/mL
- Cyclohexanol, JIS special grade, >=98.0%
- Cyclohexanol Solution in Methanol, 1000ug/mL
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless needles or viscous liquidexp.Measured value |
|---|---|
| Odour | Camphor-like odorexp.Measured value |
| Melting point | 25.9 °Cexp.Measured value |
| Boiling point | 161.8 °Cexp.Measured value |
| Density | Relative density (water = 1): 0.96exp.Measured value |
| Flash point | 62.8 °Cexp.Measured value |
| Autoignition temperature | 300 °Cexp.Measured value |
| Solubility | 3.6% (wt/wt) in water at 20 °C, miscible with ethyl acetate, linseed oil, petroleum solvents.exp.Measured value |
| Vapour pressure | Specific heat = 1.747 Joules/g, Vapor pressure = 0.15 kPa at 20 °C, 0.48 kPa at 45 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 100.16 g/molcalc.Computed value |
|---|---|
| Exact mass | 100.0888 Dacalc.Computed value |
| LogP (octanol/water) | 1.31calc.Computed value |
| Topological polar surface area | 20.23 Ųcalc.Computed value |
| Hydrogen bond donors | 1calc.Computed value |
| Hydrogen bond acceptors | 1calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 7calc.Computed value |
| Rings | 1calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Murcko scaffold
The ring system that remains when every side chain is removed
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H302Harmful if swallowed.
- H315Causes skin irritation.
- H332Harmful if inhaled.
- H335May cause respiratory irritation.
Precautionary statements (17)
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P317If swallowed: Get medical help.
- P302 + P352If on skin: Wash with plenty of water.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P317Get medical help.
- P319Get medical help if you feel unwell.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P330Rinse mouth.
- P332 + P317If skin irritation occurs: Get medical help.
- P362 + P364Take off contaminated clothing. And wash it before reuse.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1986
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidCyclohexanol suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- India, Thane ManufacturerUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- India, MumbaiUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
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- China, Zaozhuang City ManufacturerUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- Switzerland, LausanneUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- United KingdomUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- India, Mumbai ManufacturerUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- India, AnkleshwarUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- Germany, DürenUnclaimed profileCyclohexanolGrade, purity and minimum order on requestPrice on request
- Price on request
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Where suppliers are based
158 suppliers in 27 countries
- China38
- United States38
- India22
- United Kingdom8
- Germany5
- Spain5
- and 21 more countries
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Cyclohexanol price
Indicative price range per kg from live supplier offers
Suppliers quote this chemical on request. Send one free request and compare quotes side by side.
Uses and applications
What the substance is used for, by industry and function
Solvent for alkyd resins, alcohol-soluble phenolic resins, ethyl cellulose. Manufacture of celluloid, finishing textiles, in insecticides.
Oxidation of cyclohexanol to adipic acid is the most important use... 90% of adipic acid produced in the United States is used in the manufacture of nylon-6,6... The next important usage of cyclohexanol, pure or admixed with cyclohexanone as KA-oil, is in the production of caprolactam, which is used in the manufacture of nylon-6 polymer.
Chemical intermediate, a stabilizer and homogenizer for soaps and synthetic detergent emulsions, solvent for lacquers and varnishes.
As a solvent for oils ...
Read more
shellacs...
Soap making to incorporate solvents and phenolic insecticides, source of adipic acid for nylon, textile finishing, solvent for alkyd and phenolic resins, cellulosics, blending agent, lacquers, paints and varnishes, finish removers, emulsified products, leather degreasing, polishes, plasticizers, plastics, germicides.
Industrial uses: Dispersing agent, Solvent, Processing aids not otherwise specified, Diluent, Cleaning agent, Intermediate.
Consumer uses: Cleaning agent, Solvent, Dispersing agent.
Use classes: Insecticides.
Industries and functions
Cosmetic ingredient, INCI name CYCLOHEXANOL(perfuming)
Roles
- solvent
Functional uses
- Flavouring and nutrient
- Fragrance
Cosmetic functions
- Perfuming
How it is made
Cyclohexanol can be prepared in high yield by either vapor- or liquid-phase hydrogenation of phenol. Vapor-phase hydrogenation can be carried out by using a supported nickel catalyst or a nickel catalyst containing copper, cobalt, or manganese. The support is usually alumina or silicic acid. Yields as high as 98% have been reported. ... Commercial liquid-phase hydrogenation of phenol under mild conditions with a palladium on carbon catalyst gives greater than 99% yield of cyclohexanone at 90% conversion.
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By adjusting the operating conditions and changing to a Raney nickel catalyst, 99.9% selectivity for cyclohexanol can be achieved.
Liquid-phase oxidation of cyclohexane.
Boric acid modified oxidation of cyclohexane ... In the 1950s, Scientific Design (now Halcon International) developed a process in which anhydrous metaboric acid was added as a slurry to the first of several staged air oxidation vessels. The cyclohexyl hydroperoxide formed is trapped as the cyclohexyl perborate ester. The perborate ester then reacts with additional cyclohexane in the air oxidizer to yield the borate ester and additional cyclohexanol. This borate ester is relatively stable in the air oxidizer and is protected from over oxidation to ring-opened products. The ester is subsequently hydrolyzed to cyclohexanol and boric acid. The boric acid is dehydrated to metaboric acid and is recycled to the air oxidizer.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 603-009-00-3
Health and food
- EU cosmetic ingredient inventory
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Cyclohexanol is traded under.
Cyclohexanol, methylcyclohexanols and dimethylcyclohexanols
The HS code shown for Cyclohexanol is indicative (it was matched by name in the HS nomenclature). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Cyclohexanol, based on the data on this page
What is Cyclohexanol?
What is the CAS number of Cyclohexanol?
What is the molecular formula and weight of Cyclohexanol?
What is Cyclohexanol used for?
Is Cyclohexanol hazardous?
What is the HS code of Cyclohexanol?
Where can I buy Cyclohexanol?
Where can I buy Cyclohexanol in India?
What is the price of Cyclohexanol?
Guides for buyers
Practical guides that help when you source, ship or handle Cyclohexanol
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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