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Hexanal safety data

GHS hazards, precautions, first aid, handling and transport for Hexanal. A classification summary, not a safety data sheet.
CAS 66-25-1Formula C6H12O

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

GHS classification

Pictograms, signal word and hazard classes of the GHS classification

GHS02: Flammable
Flammable
GHS07: Harmful or irritant
Harmful or irritant
Signal word
Warning
321
NFPA 704 rating
health, fire, reactivity

Hazard classes and categories

  • Flam. Liq. 3
  • Skin Irrit. 2
  • Eye Irrit. 2

Hazard statements

H codes grouped by type. Percentages show the share of classification notifications that report the statement

Physical hazards

  • H226Flammable liquid and vapour.

Health hazards

  • H315Causes skin irritation.
  • H319Causes serious eye irritation.

Precautionary statements

P codes for prevention, response, storage and disposal

Prevention

  • P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P233Keep container tightly closed.
  • P240Ground and bond container and receiving equipment.
  • P241Use explosion-proof electrical, ventilating and lighting equipment.
  • P242Use non-sparking tools.
  • P243Take action to prevent static discharges.
  • P264Wash skin thoroughly after handling.
  • P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.

Response

  • P302 + P352If on skin: Wash with plenty of water.
  • P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
  • P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P321Specific treatment (see supplemental first aid instructions on the label).
  • P332 + P317If skin irritation occurs: Get medical help.
  • P337 + P317If eye irritation persists: Get medical help.
  • P362 + P364Take off contaminated clothing. And wash it before reuse.
  • P370 + P378In case of fire: Use appropriate media to extinguish.

Storage

  • P403 + P235Store in a well-ventilated place. Keep cool.

Disposal

  • P501Dispose of contents and container in accordance with local regulations.

First aid

General first aid measures. Get medical advice if you feel unwell

Skin contact
Wipe off, wash with soap and water.
Eye contact
Flush with water for at least 15 min.
If swallowed
Give large amount of water and induce vomiting.

Handling, storage and disposal

Summaries only, follow the supplier SDS for your grade

Safe handling

Skin protection: Handle with gloves. Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Storage

Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2-8 °C Storage class (TRGS 510): Flammable liquids.

Disposal

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality, potential migration in air, soil or water, effects on animal, aquatic and plant life, and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging: Dispose of as unused product.

Exposure limits and toxicity

Occupational exposure limits and toxicity data

Twelve healthy volunteers were exposed to 0, 2, and 10 ppm n-hexanal for 2 hours at rest in a balanced order. Ratings of discomfort in the eyes and nose, solvent smell, and headache increased significantly with the level of exposure. Frequency of blinking was significantly increased at 10 ppm. No effects on pulmonary function and nasal swelling were detected, except a not-significant tendency to increased nasal obstruction at 10 ppm.

Transport information

UN dangerous goods classification for road, sea and air

UN number
UN 1207
Transport hazard class
3
Packing group
III

Shipping rules depend on mode, quantity and packaging. Confirm the classification with the supplier SDS and your freight forwarder.

Supplier safety data sheets

SDS documents uploaded by suppliers who list this chemical

No supplier has uploaded an SDS for Hexanal yet. Suppliers usually send one with their quote. Request quotes

Safety questions

Quick answers about handling Hexanal safely

Is Hexanal hazardous?

Hexanal carries the GHS signal word "Warning". Main hazards: flammable liquid and vapour, causes skin irritation, causes serious eye irritation. This summary is not an SDS, always read the supplier safety data sheet.

Which GHS pictograms apply to Hexanal?

The GHS classification of Hexanal shows 2 pictograms: GHS02 (flammable), GHS07 (harmful or irritant).

What is the UN number of Hexanal?

Hexanal is transported under UN 1207, hazard class 3, packing group III. Check the supplier SDS and the current ADR, IMDG or IATA rules before shipping.

How should Hexanal be stored?

Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2-8 °C Storage class (TRGS 510): Flammable liquids.

Where can I get the SDS for Hexanal?

Ask the supplier for the safety data sheet of the exact grade you buy. Suppliers on CompoundList can attach their SDS to listings and send it with a quote. This page is a GHS classification summary, not an SDS.

GHS classification summary, not an SDS. Always check the supplier's SDS. Last updated 7 Oct 2026. Report an error

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