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Methanol chemical structure, CH4O, CAS 67-56-1
2D chemical structure

Key facts

What buyers check first

Appearance
Colorless liquid
Melting point
-97.8 °C
Boiling point
64.7 °C
Density
Relative density (water = 1): 0.79
Flash point
9.7 °C
HS code
290511
Category
Alcohol and glycol solvents
UN number
UN 1230
Illustrative photo, 200 litre steel drums of liquid in a chemical plant
Typical packagingIllustrative packaging image, not the actual product

What is Methanol?

Plain description, key identifiers and synonyms

Methanol is the primary alcohol that is the simplest aliphatic alcohol, comprising a methyl and an alcohol group. It has a role as a Mycoplasma genitalium metabolite, a fuel, an amphiprotic solvent, a mouse metabolite, an Escherichia coli metabolite and a human metabolite. It is a volatile organic compound, a primary alcohol, an alkyl alcohol and a one-carbon compound. It is a conjugate acid of a methoxide.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
methanol
CAS number
67-56-1 CAS number cross-checkedOther or deprecated CAS: 40431-63-8, 77810-22-1
EC number
200-659-6
Molecular formula
CH4O
UNII
Y4S76JWI15
MDL number
MFCD00004595
INCI name
METHYL ALCOHOL
InChIKey
OKKJLVBELUTLKV-UHFFFAOYSA-N
InChI
InChI=1S/CH4O/c1-2/h2H,1H3
SMILES (canonical and isomeric)
CO

Synonyms

  • methyl alcohol
  • wood alcohol
  • Methylol
  • Wood naphtha
  • Methyl hydroxide
  • Monohydroxymethane
  • Methylalkohol
  • Alcool methylique
  • Methyl hydrate
  • Alcohol, methyl
  • Metanolo
  • MeOH
  • Alcool metilico
  • Metylowy alkohol
  • Rcra waste number U154
  • Metanol
  • Alcohol,methyl
  • Alcohol, Wood
  • Methoxide, Sodium
  • carbinol
  • Hydroxymethane
  • Freers Elm Arrester
  • Surflo-B17
  • Wilbur-Ellis Smut-Guard
  • Coat-B1400
Show all 31 synonyms
  • X-Cide 402 Industrial Bactericide
  • Carbonal
  • Pyro alcohol
  • Alkohol metylowy
  • MetOH
  • RCRA waste no. U154

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
Colorless liquidexp.
Odour
Slight alcoholic odor when pure, repulsive, pungent odor when crudeexp.
Melting point
-97.8 °Cexp.
Boiling point
64.7 °Cexp.
Density
Relative density (water = 1): 0.79exp.
Flash point
9.7 °Cexp.
Autoignition temperature
464 °Cexp.
Solubility
Miscible with water at 25 °Cexp.
Vapour pressure
VP: 92 mm Hg at 20 °Cexp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
32.04 g/molcalc.
Exact mass
32.0262 Dacalc.
LogP (octanol/water)
-0.39calc.
Topological polar surface area
20.23 Ųcalc.
Hydrogen bond donors
1calc.
Hydrogen bond acceptors
1calc.
Rotatable bonds
0calc.
Heavy atoms
2calc.
Rings
0calc.
Aromatic rings
0calc.
Fraction sp3 carbons
1calc.
Formal charge
0calc.
Stereocentres
0calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Danger
GHS02: Flammable
Flammable
GHS06: Acute toxicity (severe)
Acute toxicity (severe)
GHS08: Serious health hazard
Serious health hazard
310NFPA 704 rating

Hazard statements

  • H225Highly flammable liquid and vapour.
  • H301Toxic if swallowed.
  • H311Toxic in contact with skin.
  • H331Toxic if inhaled.
  • H370Causes damage to organs.
Precautionary statements (27)
  • P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P233Keep container tightly closed.
  • P240Ground and bond container and receiving equipment.
  • P241Use explosion-proof electrical, ventilating and lighting equipment.
  • P242Use non-sparking tools.
  • P243Take action to prevent static discharges.
  • P260Do not breathe dust, fume, gas, mist, vapours or spray.
  • P261Avoid breathing dust, fume, gas, mist, vapours or spray.
  • P262Do not get in eyes, on skin, or on clothing.
  • P264Wash skin thoroughly after handling.
  • P270Do not eat, drink or smoke when using this product.
  • P271Use only outdoors or in a well-ventilated area.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.
  • P301 + P316If swallowed: Get emergency medical help immediately.
  • P302 + P352If on skin: Wash with plenty of water.
  • P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
  • P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • P308 + P316If exposed or concerned: Get emergency medical help immediately.
  • P316Get emergency medical help immediately.
  • P321Specific treatment (see supplemental first aid instructions on the label).
  • P330Rinse mouth.
  • P361 + P364Take off immediately all contaminated clothing. And wash it before reuse.
  • P370 + P378In case of fire: Use appropriate media to extinguish.
  • P403 + P233Store in a well-ventilated place. Keep container tightly closed.
  • P403 + P235Store in a well-ventilated place. Keep cool.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 1230
Transport hazard class
3
Packing group
II

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

Methanol suppliers

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Where suppliers are based

943 suppliers in 75 countries

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Methanol price

Indicative price range per kg from live supplier offers

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Uses and applications

What the substance is used for, by industry and function

Both oil base and water base fracturing fluids are being used in the fracturing industry. Water base, which includes alcohol-water mixtures and low strength acids, make up the majority of treating fluids. The common chemicals added to these fluids are polymers for viscosity development, crosslinkers for viscosity enhancement, pH control chemicals, gel breakers for polymer degradation following the treatment, surfactants, clay stabilizers, alcohol, bactericides, fluid loss additives and friction reducer. (Hydraulic fracturing).

Hydraulic fracturing uses a specially blended liquid which is pumped into a well under extreme pressure causing cracks in rock formations underground. These cracks in the rock then allow oil and natural gas to flow, increasing resource production. ...

Read more

Chemical Name: Methanol, Chemical Purpose: Product stabilizer and/or winterizing agent, Product Function: Corrosion inhibitor.

In 2013, the breakdown of total methanol use was formaldehyde, 31%, MTBE, 11%, acetic acid, 10%, and all other includes chloromethane, methyl methacrylate, methylamine, dimethyl terephthalate, solvents, glycol methyl ethers, antifreeze in windshield wipers, and drilling muds and fuels.

Dehydrator of natural gas, fuel for utility plants (methyl fuel), feedstock for manufacture of synthetic proteins by continuous fermentation, source of hydrogen for fuel cells, home-heating-oil extender.

Methanol is a toxic alcohol that is used industrially as a solvent, pesticide, and alternative fuel source. It also occurs naturally in humans, animals, and plants. Foods such as fresh fruits and vegetables, fruit juices, fermented beverages, and diet soft drinks containing aspartame are the primary sources of methanol in the human body.

Cosmetic ingredient, INCI name METHYL ALCOHOL(denaturant, fragrance, solvent)

Pharmacological actions

  • Solvents

Roles

  • Bronsted acid
  • Bronsted base
  • Escherichia coli metabolite
  • Mycoplasma genitalium metabolite
  • acceptor
  • acid
  • amphiprotic solvent
  • animal metabolite
  • bacterial metabolite
  • base
  • donor
  • eukaryotic metabolite
  • fuel
  • human metabolite
  • mammalian metabolite
  • metabolite
  • mouse metabolite
  • polar solvent
  • prokaryotic metabolite
  • protic solvent
  • protophilic solvent
  • solvent

Functional uses

  • Adhesion/cohesion promoter
  • Anti-slip agent
  • Chemical reaction regulator
  • Cleaning agent
  • Corrosion inhibitor
  • Fragrance
  • Processing aids not otherwise specified
  • Solubility enhancer
  • Solvent
  • Surfactant (surface active agent)
  • Thickening agent

Cosmetic functions

  • Denaturant
  • Fragrance
  • Solvent

Pharmacology

Methyl Alcohol is used as a solvent and as an intermediate in chemical synthesis. Component of deicing mixtures and preservatives. Toxic.

How it is made

Methanol is currently produced on an industrial scale exclusively by catalytic conversion of synthesis gas according to the principles of the low-pressure (LP) methanol process (5-10 MPa). The main advantages of the low-pressure processes are lower investment and production costs, improved operational reliability, and greater flexibility in the choice of plant size.

All commercial methanol processes employ a synthesis loop. ... This configuration overcomes equilibrium conversion limitations at typical catalyst operating conditions. ...

Read more

A recycle system that gives high overall conversions is feasible because product methanol and water can be removed from the loop by condensation. The makeup synthesis gas is compressed, mixed with recycled gas, and preheated against the converter effluent gas before entering the converter. The converter effluent is first used to heat the saturator water or boiler feedwater before being returned to the loop interchanger and then on to a cooler, which condenses the crude methanol-water mixture. Noncondensable gases are disengaged in a catchpot for recycle. A purge is taken from this recycle to remove excess hydrogen, methane, and other inerts. The crude methanol mixture is sent forward to the distillation section for the final purification.

Regulatory status

Inventories, regulations and trade controls that list this substance

Europe

  • EU harmonised classification (CLP Annex VI)
    Index no: 603-001-00-X

Health and food

  • EU cosmetic ingredient inventory
  • EU Cosmetics Regulation Annex III, restricted in cosmetics
    Name: METHYL ALCOHOL, Ref no: 52, Annex ref: III/52

United States

  • TSCA inventory (USA)
    Status: Active in US commerce

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code Methanol is traded under.

HS 2905.11Exact HS code

Methanol (methyl alcohol)

World exports in 2024
$10.6B
+16.6% vs 2023, imports $11.6B
2019 to 2024
Top exporters
  1. Trinidad and Tobago * partner reported16.0%
  2. Oman * partner reported14.1%
  3. Saudi Arabia12.1%
Top importers
  1. China34.3%
  2. Netherlands9.1%
  3. Brazil6.1%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for Methanol is indicative (it was matched by name in the HS nomenclature). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about Methanol, based on the data on this page

What is Methanol?

Methanol is the primary alcohol that is the simplest aliphatic alcohol, comprising a methyl and an alcohol group. It has a role as a Mycoplasma genitalium metabolite, a fuel, an amphiprotic solvent, a mouse metabolite, an Escherichia coli metabolite and a human metabolite.

What is the CAS number of Methanol?

The CAS registry number of Methanol is 67-56-1. Other or deprecated CAS numbers: 40431-63-8, 77810-22-1.

What is the molecular formula and weight of Methanol?

The molecular formula of Methanol is CH4O and its molar mass is 32.04 g/mol.

What is Methanol used for?

Both oil base and water base fracturing fluids are being used in the fracturing industry. Water base, which includes alcohol-water mixtures and low strength acids, make up the majority of treating fluids.

Is Methanol hazardous?

Methanol carries the GHS signal word "Danger". Main hazards: highly flammable liquid and vapour, toxic if swallowed, toxic in contact with skin. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of Methanol?

Methanol is usually classified under HS code 290511 (Methanol (methyl alcohol)). This is indicative, confirm it with your customs broker before shipping.

Where can I buy Methanol?

CompoundList lists 943 suppliers of Methanol in United States, India, China, United Kingdom and 71 more. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

Where can I buy Methanol in India?

137 suppliers in India list Methanol on CompoundList. Filter the suppliers list by country and send a request to compare prices, grades and delivery times.

What is the price of Methanol?

Suppliers quote Methanol on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle Methanol

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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