Methanol
Also known as methyl alcohol, wood alcohol, Methylol
Key facts
What buyers check first
- Appearance
- Colorless liquid
- Melting point
- -97.8 °C
- Boiling point
- 64.7 °C
- Density
- Relative density (water = 1): 0.79
- Flash point
- 9.7 °C
- HS code
- 290511
- Category
- Alcohol and glycol solvents
- UN number
- UN 1230

What is Methanol?
Plain description, key identifiers and synonyms
Methanol is the primary alcohol that is the simplest aliphatic alcohol, comprising a methyl and an alcohol group. It has a role as a Mycoplasma genitalium metabolite, a fuel, an amphiprotic solvent, a mouse metabolite, an Escherichia coli metabolite and a human metabolite. It is a volatile organic compound, a primary alcohol, an alkyl alcohol and a one-carbon compound. It is a conjugate acid of a methoxide.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- methanol
- CAS number
- 67-56-1 CAS number cross-checkedOther or deprecated CAS: 40431-63-8, 77810-22-1
- EC number
- 200-659-6
- Molecular formula
- CH4O
- UNII
- Y4S76JWI15
- MDL number
- MFCD00004595
- INCI name
- METHYL ALCOHOL
- InChIKey
- OKKJLVBELUTLKV-UHFFFAOYSA-N
- InChI
- InChI=1S/CH4O/c1-2/h2H,1H3
- SMILES (canonical and isomeric)
- CO
Synonyms
- methyl alcohol
- wood alcohol
- Methylol
- Wood naphtha
- Methyl hydroxide
- Monohydroxymethane
- Methylalkohol
- Alcool methylique
- Methyl hydrate
- Alcohol, methyl
- Metanolo
- MeOH
- Alcool metilico
- Metylowy alkohol
- Rcra waste number U154
- Metanol
- Alcohol,methyl
- Alcohol, Wood
- Methoxide, Sodium
- carbinol
- Hydroxymethane
- Freers Elm Arrester
- Surflo-B17
- Wilbur-Ellis Smut-Guard
- Coat-B1400
Show all 31 synonymsShow fewer synonyms
- X-Cide 402 Industrial Bactericide
- Carbonal
- Pyro alcohol
- Alkohol metylowy
- MetOH
- RCRA waste no. U154
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless liquidexp.Measured value |
|---|---|
| Odour | Slight alcoholic odor when pure, repulsive, pungent odor when crudeexp.Measured value |
| Melting point | -97.8 °Cexp.Measured value |
| Boiling point | 64.7 °Cexp.Measured value |
| Density | Relative density (water = 1): 0.79exp.Measured value |
| Flash point | 9.7 °Cexp.Measured value |
| Autoignition temperature | 464 °Cexp.Measured value |
| Solubility | Miscible with water at 25 °Cexp.Measured value |
| Vapour pressure | VP: 92 mm Hg at 20 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 32.04 g/molcalc.Computed value |
|---|---|
| Exact mass | 32.0262 Dacalc.Computed value |
| LogP (octanol/water) | -0.39calc.Computed value |
| Topological polar surface area | 20.23 Ųcalc.Computed value |
| Hydrogen bond donors | 1calc.Computed value |
| Hydrogen bond acceptors | 1calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 2calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H225Highly flammable liquid and vapour.
- H301Toxic if swallowed.
- H311Toxic in contact with skin.
- H331Toxic if inhaled.
- H370Causes damage to organs.
Precautionary statements (27)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P233Keep container tightly closed.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P242Use non-sparking tools.
- P243Take action to prevent static discharges.
- P260Do not breathe dust, fume, gas, mist, vapours or spray.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P262Do not get in eyes, on skin, or on clothing.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P316If swallowed: Get emergency medical help immediately.
- P302 + P352If on skin: Wash with plenty of water.
- P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P308 + P316If exposed or concerned: Get emergency medical help immediately.
- P316Get emergency medical help immediately.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P330Rinse mouth.
- P361 + P364Take off immediately all contaminated clothing. And wash it before reuse.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P403 + P235Store in a well-ventilated place. Keep cool.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1230
- Transport hazard class
- 3
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidMethanol suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- India, Mumbai ManufacturerUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
- India, Bharuch ManufacturerUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
- China, Dezhou ManufacturerUnclaimed profileMethyl alcoholGrade, purity and minimum order on requestPrice on request
- United States, West Palm BeachUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
- United States, WayneUnclaimed profileMethyl AlcoholGrade, purity and minimum order on requestPrice on request
- United States, Powell ManufacturerUnclaimed profileMethyl AlcoholGrade, purity and minimum order on requestPrice on request
- United States, TaylorUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
- Price on request
- Belgium, AntwerpenUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
- Turkey, Istanbul (Anatolia) ManufacturerUnclaimed profileMethanolGrade, purity and minimum order on requestPrice on request
Suppliers marked Unclaimed profile have not claimed their profile yet. They are not verified by CompoundList, their offers are price on request and details may have changed, so please confirm them with the supplier. Company representatives can claim a profile with a business email on the company's own website domain. Our team verifies each claim and sends the result by email.
Where suppliers are based
943 suppliers in 75 countries
- United States310
- India137
- China97
- United Kingdom29
- Japan25
- Germany16
- and 69 more countries
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Methanol price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
Both oil base and water base fracturing fluids are being used in the fracturing industry. Water base, which includes alcohol-water mixtures and low strength acids, make up the majority of treating fluids. The common chemicals added to these fluids are polymers for viscosity development, crosslinkers for viscosity enhancement, pH control chemicals, gel breakers for polymer degradation following the treatment, surfactants, clay stabilizers, alcohol, bactericides, fluid loss additives and friction reducer. (Hydraulic fracturing).
Hydraulic fracturing uses a specially blended liquid which is pumped into a well under extreme pressure causing cracks in rock formations underground. These cracks in the rock then allow oil and natural gas to flow, increasing resource production. ...
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Chemical Name: Methanol, Chemical Purpose: Product stabilizer and/or winterizing agent, Product Function: Corrosion inhibitor.
In 2013, the breakdown of total methanol use was formaldehyde, 31%, MTBE, 11%, acetic acid, 10%, and all other includes chloromethane, methyl methacrylate, methylamine, dimethyl terephthalate, solvents, glycol methyl ethers, antifreeze in windshield wipers, and drilling muds and fuels.
Dehydrator of natural gas, fuel for utility plants (methyl fuel), feedstock for manufacture of synthetic proteins by continuous fermentation, source of hydrogen for fuel cells, home-heating-oil extender.
Methanol is a toxic alcohol that is used industrially as a solvent, pesticide, and alternative fuel source. It also occurs naturally in humans, animals, and plants. Foods such as fresh fruits and vegetables, fruit juices, fermented beverages, and diet soft drinks containing aspartame are the primary sources of methanol in the human body.
Industries and functions
Cosmetic ingredient, INCI name METHYL ALCOHOL(denaturant, fragrance, solvent)
Pharmacological actions
- Solvents
Roles
- Bronsted acid
- Bronsted base
- Escherichia coli metabolite
- Mycoplasma genitalium metabolite
- acceptor
- acid
- amphiprotic solvent
- animal metabolite
- bacterial metabolite
- base
- donor
- eukaryotic metabolite
- fuel
- human metabolite
- mammalian metabolite
- metabolite
- mouse metabolite
- polar solvent
- prokaryotic metabolite
- protic solvent
- protophilic solvent
- solvent
Functional uses
- Adhesion/cohesion promoter
- Anti-slip agent
- Chemical reaction regulator
- Cleaning agent
- Corrosion inhibitor
- Fragrance
- Processing aids not otherwise specified
- Solubility enhancer
- Solvent
- Surfactant (surface active agent)
- Thickening agent
Cosmetic functions
- Denaturant
- Fragrance
- Solvent
Pharmacology
Methyl Alcohol is used as a solvent and as an intermediate in chemical synthesis. Component of deicing mixtures and preservatives. Toxic.
How it is made
Methanol is currently produced on an industrial scale exclusively by catalytic conversion of synthesis gas according to the principles of the low-pressure (LP) methanol process (5-10 MPa). The main advantages of the low-pressure processes are lower investment and production costs, improved operational reliability, and greater flexibility in the choice of plant size.
All commercial methanol processes employ a synthesis loop. ... This configuration overcomes equilibrium conversion limitations at typical catalyst operating conditions. ...
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A recycle system that gives high overall conversions is feasible because product methanol and water can be removed from the loop by condensation. The makeup synthesis gas is compressed, mixed with recycled gas, and preheated against the converter effluent gas before entering the converter. The converter effluent is first used to heat the saturator water or boiler feedwater before being returned to the loop interchanger and then on to a cooler, which condenses the crude methanol-water mixture. Noncondensable gases are disengaged in a catchpot for recycle. A purge is taken from this recycle to remove excess hydrogen, methane, and other inerts. The crude methanol mixture is sent forward to the distillation section for the final purification.
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 603-001-00-X
Health and food
- EU cosmetic ingredient inventory
- EU Cosmetics Regulation Annex III, restricted in cosmeticsName: METHYL ALCOHOL, Ref no: 52, Annex ref: III/52
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Methanol is traded under.
Methanol (methyl alcohol)
- Trinidad and Tobago * partner reported16.0%
- Oman * partner reported14.1%
- Saudi Arabia12.1%
- China34.3%
- Netherlands9.1%
- Brazil6.1%
* Partner reported figures, a lower bound.
The HS code shown for Methanol is indicative (it was matched by name in the HS nomenclature). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Methanol, based on the data on this page
What is Methanol?
What is the CAS number of Methanol?
What is the molecular formula and weight of Methanol?
What is Methanol used for?
Is Methanol hazardous?
What is the HS code of Methanol?
Where can I buy Methanol?
Where can I buy Methanol in India?
What is the price of Methanol?
Guides for buyers
Practical guides that help when you source, ship or handle Methanol
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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