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Acids and bases

Acetic acid vs citric acid

Acetic acid (C2H4O2, CAS 64-19-7) and citric acid (C6H8O7, CAS 77-92-9) are both listed under acidulants and acidity regulators.

Acetic acid has a molar mass of 60.05 g/mol, citric acid 192.12 g/mol.

Measured melting points are 16.6 °C for acetic acid and 153 °C for citric acid.

Acetic acid carries the GHS signal word Danger, citric acid Warning.

On CompoundList, 1,107 suppliers list acetic acid and 1,149 suppliers list citric acid.

Data last updated 7 October 2026

Acetic acid and citric acid compared side by side
Acetic acid chemical structure, C2H4O2, CAS 64-19-7
Acetic acid
Citric acid chemical structure, C6H8O7, CAS 77-92-9
Citric acid
Identity
Name in our databaseAcetic acidCitric acid
CAS number64-19-777-92-9
Molecular formulaC2H4O2C6H8O7
Molar mass60.05 g/mol192.12 g/mol
IUPAC nameacetic acid2-hydroxypropane-1,2,3-tricarboxylic acid
EC number200-580-7201-069-1
Physical properties
AppearanceClear, colorless liquidCrystals, monoclinic holohedra, crystallizes from hot concentrated aqueous solution
Melting point16.6 °C153 °C
Boiling point117.9 °CDecomposes
Density1.0446 g/cm³ at 25 °C1.665 g/cm³ at 20 °C
Flash point39 °C100 °C
SolubilityMiscible with waterIn water, 3.83 × 10⁺⁵ mg/L at 25 °C
LogP (octanol/water)Computed from the structure0.09-1.25
Safety (GHS)
Signal wordDangerWarning
Pictograms
GHS02: Flammable
GHS05: Corrosive
GHS07: Harmful or irritant
Hazard statements
  • H226 Flammable liquid and vapour.
  • H314 Causes severe skin burns and eye damage.
  • H319 Causes serious eye irritation.
  • H335 May cause respiratory irritation.
UN numberUN 2789Not recorded
Uses and classification
Uses and functions
  • Fragrance ingredients
  • Preservatives
  • Acidulants and acidity regulators
  • Acidifiers
  • Monomers
  • Bronsted acid
  • Cardiovascular drugs
  • Fragrance ingredients
  • Acidulants and acidity regulators
  • Acidifiers
  • Builders and chelants
  • Additive
CategoryFood and feed additives › Acidulants and acidity regulatorsFood and feed additives › Acidulants and acidity regulators
HS code291521Acetic acid291814Citric acid
Market on CompoundList
Suppliers1,107 suppliers1,149 suppliers
Supplier countries73 countries, most in India, United States, China85 countries, most in India, United States, China
Price rangeOnly prices set by suppliers who manage their own profilePrice on requestPrice on request

Measured and computed values as shown on each chemical page, plus live listings on CompoundList. Details may have changed, please confirm them with the supplier. Safety data is a summary, not an SDS.

More comparisons

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