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Beryllium hydroxide

Also known as Beryllium dihydroxide, Beryllium hydrate, beryllium(II) hydroxide

CAS 13327-32-7Formula H2BeO2Molar mass 43.03 g/molEC 236-368-6
Beryllium hydroxide chemical structure, H2BeO2, CAS 13327-32-7
2D chemical structure

Key facts

What buyers check first

Appearance
White powder or crystals (alpha), colorless tetrahedral crystals (beta)
Melting point
Ca. 200
Density
1.92 g/cmยณ (alpha)
Solubility
Slightly soluble in water, alkali solutions, soluble in acid solutions (alpha)
HS code
282590
Category
Hydroxides and bases
Illustrative photo, fine white powder in a clear glass bottle on a laboratory bench
Typical packagingIllustrative packaging image, not the actual product

What is Beryllium hydroxide?

Plain description, key identifiers and synonyms

Beryllium dihydroxide is a beryllium hydroxide.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
beryllium dihydroxide
CAS number
13327-32-7 CAS number cross-checked
EC number
236-368-6
Molecular formula
H2BeO2
UNII
2X0LRF1T6Q
MDL number
MFCD00049856
InChIKey
WPJWIROQQFWMMK-UHFFFAOYSA-L
InChI
InChI=1S/Be.2H2O/h;2*1H2/q+2;;/p-2
SMILES (canonical and isomeric)
[Be+2].[OH-].[OH-]

Synonyms

  • Beryllium dihydroxide
  • Beryllium hydrate
  • beryllium(II) hydroxide
  • beryllium(2+) hydroxide
  • beryllium(2+) ion dihydroxide
  • BERYLLIUM HYDROXIDE (Be(OH)2)
  • Beryllium hydroxide (Be(OH)a2)

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
White powder or crystals (alpha), colorless tetrahedral crystals (beta)exp.
Melting point
Ca. 200exp.
Density
1.92 g/cmยณ (alpha)exp.
Solubility
Slightly soluble in water, alkali solutions, soluble in acid solutions (alpha)exp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
43.03 g/molcalc.
Exact mass
43.0177 Dacalc.
LogP (octanol/water)
-0.73calc.
Topological polar surface area
60 ร…ยฒcalc.
Hydrogen bond donors
0calc.
Hydrogen bond acceptors
2calc.
Rotatable bonds
0calc.
Heavy atoms
3calc.
Rings
0calc.
Aromatic rings
0calc.
Fraction sp3 carbons
0calc.
Formal charge
0calc.
Stereocentres
0calc.
Components
3calc.

Calculated for screening. Confirm critical figures with the supplier.

Safety and hazards

GHS classification summary, not a safety data sheet

GHS classification
Hazard pictograms

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

Beryllium hydroxide suppliers

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All 2 suppliers

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Where suppliers are based

2 suppliers in 1 country

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Beryllium hydroxide price

Indicative price range per kg from live supplier offers

No published prices right now

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Uses and applications

What the substance is used for, by industry and function

The basic raw material for processing into beryllium metal, copper-beryllium and other alloys, and beryllia for ceramic products.

Manufacture of beryllium and beryllium oxide.

Feed material for products such as ... beryllium alloys.

Most beryllium compounds, with the exception of beryllium oxide, have no commercial or technical use, and are only encountered in the production of beryllium metal as intermediary materials ... or as laboratory chemicals. (Beryllium compounds).

Industrial uses: Other.

Pharmacology

Beryllium Hydroxide is a white colored, crystalline, inorganic compound that emits toxic fumes of beryllium oxides upon heating. Beryllium hydroxide is mainly used to produce beryllium metal and alloys. Inhalation exposure to its dust irritates the nose, throat and lungs and can cause pneumonitis. Prolonged exposure can result in a chronic beryllium disease called berylliosis causing granuloma and fibrosis formation in the lungs. Beryllium is associated with an increased risk of developing lung cancer. (NCI05)

How it is made

The sulfate process, the only process currently used, involves either alkali or heat treatment of beryl. With alkali treatment, which was discontinued in the 1960s, finely ground beryl was heated until fusion or sintered below the melting-point with suitable alkalis, such as hydroxides and carbonates of sodium, potassium and calcium. With heat treatment, which has been used since the 1970s, beryl is melted without additives and quenched with water, the water insoluble portion, a solid solution with silicon dioxide, is reheated to 900 ยฐC to render a total of 90-95% of the beryl soluble.

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Heat-treated or alkali-treated beryl is then extracted with sulfuric acid and carried through several additional purification steps to produce a fine-grained, readily filtered beryllium hydroxide

In the fluoride process, which was discontinued in the 1970s, beryl was sintered together with sodium hexafluorosilicate, or the less expensive sodium fluoroferrate, at 700-800 ยฐC to convert beryllium oxide to a water-soluble salt, sodium beryllium tetrafluoride (Na2BeF4). The reaction product was then leached with water at room temperature and precipitated from the purified solution with caustic soda as beryllium hydroxide.

The beryllium-poor bertrandite ores (< or = to 0.5-0.8% BeO) mined in the USA since 1960 cannot be smelted economically by conventional methods, and a less complicated procedure has been developed in which a very pure beryllium hydroxide is produced by liquid-liquid extraction.

Regulatory status

Inventories, regulations and trade controls that list this substance

United States

  • TSCA inventory (USA)
    Status: Active in US commerce

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code Beryllium hydroxide is traded under.

HS 2825.90Indicative HS code

Inorganic bases not elsewhere classified in heading 2825

World exports in 2024
$972M
+5.4% vs 2023, imports $3.4B
2019 to 2024
Top exporters
  1. China28.5%
  2. United States23.7%
  3. Brazil10.8%
Top importers
  1. South Korea77.2%
  2. Japan4.3%
  3. United States3.8%
Reported customs values in USD, not prices.Full trade data

The HS code shown for Beryllium hydroxide is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about Beryllium hydroxide, based on the data on this page

What is Beryllium hydroxide?

Beryllium dihydroxide is a beryllium hydroxide.

What is the CAS number of Beryllium hydroxide?

The CAS registry number of Beryllium hydroxide is 13327-32-7.

What is the molecular formula and weight of Beryllium hydroxide?

The molecular formula of Beryllium hydroxide is H2BeO2 and its molar mass is 43.03 g/mol.

What is Beryllium hydroxide used for?

The basic raw material for processing into beryllium metal, copper-beryllium and other alloys, and beryllia for ceramic products. Manufacture of beryllium and beryllium oxide. Feed material for products such as ... beryllium alloys.

Is Beryllium hydroxide hazardous?

No GHS hazard classification for Beryllium hydroxide is recorded on CompoundList yet. That does not prove it is safe. Always read the supplier safety data sheet.

What is the HS code of Beryllium hydroxide?

Beryllium hydroxide is usually classified under HS code 282590 (Hydrazine and hydroxylamine and their inorganic salts, other inorganic bases, otherโ€ฆ). This is indicative, confirm it with your customs broker before shipping.

Where can I buy Beryllium hydroxide?

CompoundList lists 2 suppliers of Beryllium hydroxide in United States. Send one free request to get and compare quotes. Your contact details stay private until you accept a quote.

What is the price of Beryllium hydroxide?

Suppliers quote Beryllium hydroxide on request because prices depend on grade, purity, quantity and destination. A free request on CompoundList gets you several quotes to compare.

Guides for buyers

Practical guides that help when you source, ship or handle Beryllium hydroxide

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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