Dimethoxymethane
Also known as Methylal, Formal, Methane, dimethoxy-
Key facts
What buyers check first
- Appearance
- Colorless, clear liquid
- Melting point
- -105 °C
- Boiling point
- 41.6 °C
- Density
- 0.86 g/cm³
- Flash point
- -32 °C
- HS code
- 291100
- Category
- Cosmetic ingredients
- UN number
- UN 1234

What is Dimethoxymethane?
Plain description, key identifiers and synonyms
Dimethoxymethane is an acetal that is the dimethyl acetal derivative of formaldehyde. It is a diether and an acetal. It is functionally related to a methanediol.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- dimethoxymethane
- CAS number
- 109-87-5 CAS number cross-checked
- EC number
- 203-714-2
- Molecular formula
- C3H8O2
- UNII
- 7H1M4G2NUE
- MDL number
- MFCD00008495
- INCI name
- METHYLAL
- InChIKey
- NKDDWNXOKDWJAK-UHFFFAOYSA-N
- InChI
- InChI=1S/C3H8O2/c1-4-3-5-2/h3H2,1-2H3
- SMILES (canonical and isomeric)
- COCOC
Synonyms
- Methylal
- Formal
- Methane, dimethoxy-
- Formaldehyde dimethyl acetal
- Dimethyl formal
- Anesthenyl
- 2,4-Dioxapentane
- Methylene dimethyl ether
- Bis(methoxy)methane
- Methoxymethyl methyl ether
- Formaldehyde methyl ketal
- Metylal
- Formaldehyde dimethylacetal
- Dimethoxy methane
- bis(methyloxy)methane
- Methylene glycol dimethylether
- Dimethylformal
- Methylene Glycol Dimethyl Ether
- Methylenedioxydimethane
- Dimethoxymethane 99.5%
- Dimethylacetal formaldehyde
- (CH3O)2CH2
- UN 1234
- Dimethoxymethane, ReagentPlus(R), 99%
- Methylal [UN1234] [Flammable liquid]
Show all 27 synonymsShow fewer synonyms
- Formaldehyde dimethyl acetal, analytical standard
- Formaldehyde dimethyl acetal, absolute, over molecular sieve (H2O <=0.01%), >=99.0% (GC)
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless, clear liquidexp.Measured value |
|---|---|
| Odour | CHLOROFORM ODORexp.Measured value |
| Taste | PUNGENT TASTEexp.Measured value |
| Melting point | -105 °Cexp.Measured value |
| Boiling point | 41.6 °Cexp.Measured value |
| Density | 0.86 g/cm³exp.Measured value |
| Flash point | -32 °Cexp.Measured value |
| Autoignition temperature | 237 °Cexp.Measured value |
| Solubility | MISCIBLE WITH ALCOHOL, ETHER, OILS, SOL IN 3 PARTS WATERexp.Measured value |
| Vapour pressure | 400 MM HG AT 25 °Cexp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 76.10 g/molcalc.Computed value |
|---|---|
| Exact mass | 76.0524 Dacalc.Computed value |
| LogP (octanol/water) | 0.24calc.Computed value |
| Topological polar surface area | 18.46 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 2calc.Computed value |
| Rotatable bonds | 2calc.Computed value |
| Heavy atoms | 5calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 1calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H225Highly flammable liquid and vapour.
- H315Causes skin irritation.
- H319Causes serious eye irritation.
- H335May cause respiratory irritation.
Precautionary statements (25)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P233Keep container tightly closed.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P242Use non-sparking tools.
- P243Take action to prevent static discharges.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
- P271Use only outdoors or in a well-ventilated area.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P302 + P352If on skin: Wash with plenty of water.
- P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P351 + P338If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P319Get medical help if you feel unwell.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P332 + P317If skin irritation occurs: Get medical help.
- P337 + P317If eye irritation persists: Get medical help.
- P362 + P364Take off contaminated clothing. And wash it before reuse.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P403 + P235Store in a well-ventilated place. Keep cool.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1234
- Transport hazard class
- 3
- Packing group
- II
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidDimethoxymethane suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- India, Navi Mumbai ManufacturerUnclaimed profileDimethoxymethaneGrade, purity and minimum order on requestPrice on request
- China, ShanghaiUnclaimed profileMethylalGrade, purity and minimum order on requestPrice on request
- India ManufacturerUnclaimed profileMethylalGrade, purity and minimum order on requestPrice on request
- Price on request
- Germany, DürenUnclaimed profileMethylalGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileDimethoxymethaneGrade, purity and minimum order on requestPrice on request
- China, XuchangUnclaimed profileMethylalGrade, purity and minimum order on requestPrice on request
- France, Saint-Thibault-des-VignesUnclaimed profileDimethoxymethaneGrade, purity and minimum order on requestPrice on request
- Price on request
- ChinaUnclaimed profileDimethoxymethaneGrade, purity and minimum order on requestPrice on request
Suppliers marked Unclaimed profile have not claimed their profile yet. They are not verified by CompoundList, their offers are price on request and details may have changed, so please confirm them with the supplier. Company representatives can claim a profile with a business email on the company's own website domain. Our team verifies each claim and sends the result by email.
Where suppliers are based
35 suppliers in 13 countries
- China12
- United States7
- India4
- United Kingdom2
- Poland2
- Belgium1
- and 7 more countries
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Dimethoxymethane price
Indicative price range per kg from live supplier offers
Suppliers quote this chemical on request. Send one free request and compare quotes side by side.
Uses and applications
What the substance is used for, by industry and function
In perfumery, manufacture artificial resins, reaction medium for grignard & reppe reactions.
Externally as ointment and internally as an anaesthetic and hypnotic.
Special purposes fuel, solvent for adhesives & coatings, in org syntheses.
In methacrylate mfg.
Industrial uses: Intermediate, Propellants, non-motive (blowing agents), Solvent, Monomers.
Consumer uses: Solvent, Propellants, non-motive (blowing agents).
Use classes: Cosmetics.
Cosmetic ingredient, INCI name METHYLAL(solvent)
Functional uses
- Flavouring and nutrient
- Solvent
Cosmetic functions
- Solvent
How it is made
By catalytic vapor-phase oxidn of methanol in presence of small amt of hydrochloric acid, from methanol & formaldehyde. From paraformaldehyde + methanol in presence of calcium chloride + hydrochloric acid.
Regulatory status
Inventories, regulations and trade controls that list this substance
Health and food
- EU cosmetic ingredient inventory
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Dimethoxymethane is traded under.
Acetals and hemiacetals whether or not with other oxygen function, and their halogenated, sulphonated…
The HS code shown for Dimethoxymethane is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Dimethoxymethane, based on the data on this page
What is Dimethoxymethane?
What is the CAS number of Dimethoxymethane?
What is the molecular formula and weight of Dimethoxymethane?
What is Dimethoxymethane used for?
Is Dimethoxymethane hazardous?
What is the HS code of Dimethoxymethane?
Where can I buy Dimethoxymethane?
Where can I buy Dimethoxymethane in India?
What is the price of Dimethoxymethane?
Guides for buyers
Practical guides that help when you source, ship or handle Dimethoxymethane
- Article, FormulationHow to choose a cosmetic emulsifierA structured way to choose an emulsifier for creams and lotions: emulsion type, HLB and its limits, emulsifier families, formula fit, stability testing and what to ask suppliers.Read
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
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