Trichlorosilane
Also known as Silane A-19, Silane, trichloro-, Silici-chloroforme
Key facts
What buyers check first
- Appearance
- Colorless liquid
- Melting point
- -126.5 °C
- Boiling point
- 31.8 °C
- Density
- Relative density (water = 1): 1.34
- Flash point
- -14 °C
- HS code
- 281219
- Category
- Chlorides and other halides
- UN number
- UN 1295

What is Trichlorosilane?
Plain description, key identifiers and synonyms
Trichlorosilane appears as a colorless fuming liquid with a pungent odor. Flash point 7 °F. Vapor and liquid cause burns. More dense than water. Vapors are heavier than air.
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- trichlorosilane
- CAS number
- 10025-78-2 CAS number cross-checked
- EC numbers
- 233-042-5, 419-930-7
- Molecular formula
- HCl3Si
- UNII
- QZY2645L6V
- MDL number
- MFCD00011518
- InChIKey
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N
- InChI
- InChI=1S/Cl3HSi/c1-4(2)3/h4H
- SMILES (canonical and isomeric)
- [SiH](Cl)(Cl)Cl
Synonyms
- Silane A-19
- Silane, trichloro-
- Silici-chloroforme
- Siliciumchloroform
- Silicochloroform
- Silicon chloride hydride (SiHCl3)
- Trichloorsilaan
- Trichloromonosilane
- Trichlorsilan
- Triclorosilano
- Cl3HSi
- Cl3SiH
- HSiCl3
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless liquidexp.Measured value |
|---|---|
| Odour | ACRID ODORexp.Measured value |
| Melting point | -126.5 °Cexp.Measured value |
| Boiling point | 31.8 °Cexp.Measured value |
| Density | Relative density (water = 1): 1.34exp.Measured value |
| Flash point | -14 °Cexp.Measured value |
| Autoignition temperature | 182 °Cexp.Measured value |
| Solubility | Solubility in water: reactionexp.Measured value |
| Vapour pressure | Vapor pressure, kPa at 20 °C: 65.8exp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 135.45 g/molcalc.Computed value |
|---|---|
| Exact mass | 133.8913 Dacalc.Computed value |
| LogP (octanol/water) | 1.42calc.Computed value |
| Topological polar surface area | 0 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 0calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 4calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 0calc.Computed value |
| Formal charge | 0calc.Computed value |
| Stereocentres | 0calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H224Extremely flammable liquid and vapour.
- H260In contact with water releases flammable gases which may ignite spontaneously.
- H302Harmful if swallowed.
- H314Causes severe skin burns and eye damage.
- H318Causes serious eye damage.
- H331Toxic if inhaled.
Precautionary statements (33)
- P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P223Do not allow contact with water.
- P231 + P232Handle and store contents under inert gas. Protect from moisture.
- P233Keep container tightly closed.
- P240Ground and bond container and receiving equipment.
- P241Use explosion-proof electrical, ventilating and lighting equipment.
- P242Use non-sparking tools.
- P243Take action to prevent static discharges.
- P260Do not breathe dust, fume, gas, mist, vapours or spray.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P264 + P265Wash skin thoroughly after handling. Do not touch eyes.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P317If swallowed: Get medical help.
- P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
- P302 + P335 + P334If on skin: Brush off loose particles from skin. Immerse in cool water or wrap in wet bandages.
- P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
- P303 + P361 + P353If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P316Get emergency medical help immediately.
- P317Get medical help.
- P321Specific treatment (see supplemental first aid instructions on the label).
- P330Rinse mouth.
- P363Wash contaminated clothing before reuse.
- P370 + P378In case of fire: Use appropriate media to extinguish.
- P402 + P404Store in a dry place. Store in a closed container.
- P403 + P233Store in a well-ventilated place. Keep container tightly closed.
- P403 + P235Store in a well-ventilated place. Keep cool.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 1295
- Transport hazard class
- 4.3
- Packing group
- I
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidTrichlorosilane suppliers
Sponsored listings first, then the documented ranking: membership, verification, replies, completeness, freshness and ratings
- China, TianjinUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- ChinaUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- China, HangzhouUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- China, Wuxi ManufacturerUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- Hong KongUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- China, ChangzhouUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- China ManufacturerUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
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- ChinaUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
- China ManufacturerUnclaimed profileTrichlorosilaneGrade, purity and minimum order on requestPrice on request
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Where suppliers are based
27 suppliers in 6 countries
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Trichlorosilane price
Indicative price range per kg from live supplier offers
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Uses and applications
What the substance is used for, by industry and function
In manufacture of transistors.
In organic synthesis.
In the production of high purity silicon metal and as an intermediate for silane adhesion promoters, coupling agents silicon resin intermediates, and surface treatment.
The major application for trichlorosilane is as a raw material for producing high-purity polycrystalline silicon, which eventually becomes the polished silicon wafers used in semiconductor production.
Industrial uses: Intermediate, Viscosity modifiers.
Industries and functions
How it is made
Reaction of hydrogen chloride gas passed through silicon or copper silicon powder in fluidized bed.
Prepared from Si and HCl or from SiH4 and HCl in presence of AlCl3.
Trichlorosilane is made by passing hydrogen chloride through silicon powder at a moderate temperature (280 - 300 °C).
Regulatory status
Inventories, regulations and trade controls that list this substance
Europe
- EU harmonised classification (CLP Annex VI)Index no: 014-001-00-9
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Trichlorosilane is traded under.
Chlorides and chloride oxides, other
- South Korea32.7%
- Japan21.7%
- Germany16.4%
- China27.8%
- Singapore21.4%
- South Korea19.0%
The HS code shown for Trichlorosilane is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Trichlorosilane, based on the data on this page
What is Trichlorosilane?
What is the CAS number of Trichlorosilane?
What is the molecular formula and weight of Trichlorosilane?
What is Trichlorosilane used for?
Is Trichlorosilane hazardous?
What is the HS code of Trichlorosilane?
Where can I buy Trichlorosilane?
What is the price of Trichlorosilane?
Guides for buyers
Practical guides that help when you source, ship or handle Trichlorosilane
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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