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2,6-Dichlorophenol chemical structure, C6H4Cl2O, CAS 87-65-0
2D chemical structure

Key facts

What buyers check first

Appearance
White crystals from petroleum ether
Melting point
68.5 °C
Boiling point
217.8 to 220
Density
1.653 g/cm³ at 20 °C
Solubility
In water, 2.65 × 10⁺³ mg/l at 25 °C
HS code
290819
Category
Impurities and reference standards
UN number
UN 2020
Illustrative photo, colourless crystals in an open woven sack in a warehouse
Typical packagingIllustrative packaging image, not the actual product

What is 2,6-Dichlorophenol?

Plain description, key identifiers and synonyms

2,6-dichlorophenol is a dichlorophenol with the chloro substituents at positions 2 and 6.

Identifiers

Registry numbers, names and line notations, tap to copy

IUPAC name
2,6-dichlorophenol
CAS number
87-65-0 CAS number cross-checkedOther or deprecated CAS: 25511-62-0
EC number
201-761-3
Molecular formula
C6H4Cl2O
UNII
Q7E9K52W7E
MDL number
MFCD00002176
InChIKey
HOLHYSJJBXSLMV-UHFFFAOYSA-N
InChI
InChI=1S/C6H4Cl2O/c7-4-2-1-3-5(8)6(4)9/h1-3,9H
SMILES (canonical and isomeric)
C1=CC(=C(C(=C1)Cl)O)Cl

Synonyms

  • Phenol, 2,6-dichloro-
  • 2,6-Dichlorfenol
  • 2,6-DCP
  • RCRA waste number U082
  • 2,6-Dichlorophenol (2,6-DCP)
  • 2,6-dichloro-phenol
  • 2,6-DCP, 2,6-Dichlorophenol
  • 2,6-Dichlorophenol 100 microg/mL in Methanol
  • Dichlorophenol, 2,6-
  • RCRA waste no. U082
  • 2,6-Dichlorophenol, NSC 60647, Phloroglucinol Impurity I
  • Phloroglucinol EP Impurity I
  • DUB
  • 2,6 dichlorophenol
  • 2.6-dichlorophenol
  • Phloroglucinol Impurity I
  • 2,6-Dichlorophenol, 98%
  • 2,6-Dichlorophenol, 99%
  • 4-06-00-00949 (Beilstein Handbook Reference)
  • Lofexidine metabolite (2,6 dcp)
  • 2,6-Dichlorophenol 10 microg/mL in Methanol
  • 2,6-Dichlorophenol 1000 microg/mL in Methanol
  • 2,6-Dichlorophenol Solution in Methanol, 1000_g/mL
  • 2,6-Dichlorophenol, PESTANAL(R), analytical standard

Physical and chemical properties

Measured values and descriptors computed from the structure

Physical and chemical properties

Measured values, check the supplier specification for your grade

Appearance
White crystals from petroleum etherexp.
Taste
Taste threshold in water 0.2 ug/lexp.
Melting point
68.5 °Cexp.
Boiling point
217.8 to 220exp.
Density
1.653 g/cm³ at 20 °Cexp.
Solubility
In water, 2.65 × 10⁺³ mg/l at 25 °Cexp.
Vapour pressure
1 mm Hg @ 59.5 °C, 10 mm Hg @ 101.0 °C, 40 mm Hg @ 131.6 °C, 100 mm Hg @ 154.6 °C, 400 mm Hg @ 197.7 °C, 760 mm Hg @ 220.0 °Cexp.

Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.

Computed descriptors

Calculated from the structure, useful for screening and formulation

Molecular weight
163.00 g/molcalc.
Exact mass
161.9639 Dacalc.
LogP (octanol/water)
2.7calc.
Topological polar surface area
20.23 Ųcalc.
Hydrogen bond donors
1calc.
Hydrogen bond acceptors
1calc.
Rotatable bonds
0calc.
Heavy atoms
9calc.
Rings
1calc.
Aromatic rings
1calc.
Fraction sp3 carbons
0calc.
Formal charge
0calc.
Stereocentres
0calc.
Lipinski rule of five
Passes (0 violations)calc.

Calculated for screening. Confirm critical figures with the supplier.

Murcko scaffold

The ring system that remains when every side chain is removed

Murcko scaffold of this chemical, c1ccccc1

c1ccccc1

1 ring, 6 atoms, the Benzene ring system.

485,677 other chemicals share this scaffold

Safety and hazards

GHS classification summary, not a safety data sheet

GHS signal word
Danger
GHS05: Corrosive
Corrosive
GHS09: Hazardous to the environment
Hazardous to the environment

Hazard statements

  • H314Causes severe skin burns and eye damage.
  • H411Toxic to aquatic life with long lasting effects.
Precautionary statements (14)
  • P260Do not breathe dust, fume, gas, mist, vapours or spray.
  • P264Wash skin thoroughly after handling.
  • P273Avoid release to the environment.
  • P280Wear protective gloves, protective clothing, eye protection and face protection.
  • P301 + P330 + P331If swallowed: Rinse mouth. Do not induce vomiting.
  • P302 + P361 + P354If on skin: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
  • P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • P305 + P354 + P338If in eyes: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P316Get emergency medical help immediately.
  • P321Specific treatment (see supplemental first aid instructions on the label).
  • P363Wash contaminated clothing before reuse.
  • P391Collect spillage.
  • P405Store locked up.
  • P501Dispose of contents and container in accordance with local regulations.
UN number
UN 2020

GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.

Full safety data and first aid

2,6-Dichlorophenol suppliers

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2,6-Dichlorophenol price

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Uses and applications

What the substance is used for, by industry and function

Chemical intermediate for 2,4,6-trichlorophenol.

How it is made

Industrially by chlorination of phenol with chlorine gas in a melt in cast-iron reactors. The isomer distribution in the product may be adjusted to market demands by the chlorination level and by recycling various intermediates. The yield, based on chlorine and phenol, is greater than 95%. (Mono-, Di-, and Trichlorophenols with No Chlorine in a Meta Position)

Treatment of 2-chlorophenol with liquid sulfur dioxide, followed by gaseous chlorine with heat

Obtained by chlorinating o-chlorophenol in the presence of a catalytic quantity of an amine, with or without a solvent medium, giving a yield of 90%.

Regulatory status

Inventories, regulations and trade controls that list this substance

United States

  • TSCA inventory (USA)
    Status: Active in US commerce, Regulatory flags: Section 4 test rule or order

HS code and trade data

Customs classification and reported world trade statistics

Global trade

World import and export statistics for the HS code 2,6-Dichlorophenol is traded under.

HS 2908.19Indicative HS code

Derivatives containing only halogen substituents and their salts, other

World exports in 2024
$452M
−8.2% vs 2023, imports $435M
2019 to 2024
Top exporters
  1. Jordan * partner reported36.5%
  2. Israel29.6%
  3. China6.5%
Top importers
  1. China58.6%
  2. South Korea10.3%
  3. United States5.5%

* Partner reported figures, a lower bound.

Reported customs values in USD, not prices.Full trade data

The HS code shown for 2,6-Dichlorophenol is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.

Frequently asked questions

Quick answers about 2,6-Dichlorophenol, based on the data on this page

What is 2,6-Dichlorophenol?

2,6-dichlorophenol is a dichlorophenol with the chloro substituents at positions 2 and 6.

What is the CAS number of 2,6-Dichlorophenol?

The CAS registry number of 2,6-Dichlorophenol is 87-65-0. Other or deprecated CAS numbers: 25511-62-0.

What is the molecular formula and weight of 2,6-Dichlorophenol?

The molecular formula of 2,6-Dichlorophenol is C6H4Cl2O and its molar mass is 163.00 g/mol.

What is 2,6-Dichlorophenol used for?

Chemical intermediate for 2,4,6-trichlorophenol.

Is 2,6-Dichlorophenol hazardous?

2,6-Dichlorophenol carries the GHS signal word "Danger". Main hazards: causes severe skin burns and eye damage, toxic to aquatic life with long lasting effects. This summary is not an SDS, always read the supplier safety data sheet.

What is the HS code of 2,6-Dichlorophenol?

2,6-Dichlorophenol is usually classified under HS code 290819 (Derivatives containing only halogen substituents and their salts, other). This is indicative, confirm it with your customs broker before shipping.

Where can I buy 2,6-Dichlorophenol?

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Where can I buy 2,6-Dichlorophenol in India?

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What is the price of 2,6-Dichlorophenol?

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Guides for buyers

Practical guides that help when you source, ship or handle 2,6-Dichlorophenol

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Data last updated 7 Oct 2026. Details may have changed, please confirm them with the supplier. Report an error on this page
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