Lead tetraacetate
Also known as Plumbic acetate, Lead(IV) acetate, Lead tetracetate
Key facts
What buyers check first
- Appearance
- Colorless monoclinic prisms from glacial acetic acid
- Melting point
- 175 to 180
- Density
- 2.228 at 17 °C/4 °C
- Solubility
- Soluble in hot glacial acetic acid, benzene, chloroform, tetrachloroethane, nitrobenzene.
- HS code
- 291529
- Category
- Oxidizing and reducing agents
- UN number
- UN 2291

What is Lead tetraacetate?
Plain description, key identifiers and synonyms
Faintly pink wet crystals with an odor of vinegar. (USCG, 1999)
Identifiers
Registry numbers, names and line notations, tap to copy
- IUPAC name
- lead(2+) tetraacetate
- CAS number
- 546-67-8 CAS number cross-checked
- EC number
- 208-908-0
- Molecular formula
- C8H12O8Pb-2
- UNII
- CFN24B03DB
- InChIKey
- ACKFDYCQCBEDNU-UHFFFAOYSA-J
- InChI
- InChI=1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+2/p-4
- SMILES (canonical and isomeric)
- CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Pb+2]
Synonyms
- Plumbic acetate
- Lead(IV) acetate
- Lead tetracetate
- Lead acetate, tetra-
- Lead acetate (Pb(OAc)4)
- Acetic acid, lead(4+) salt
- Lead acetate (Pb(O2C2H3)4)
- Lead (IV) Acetate
- lead(4+) tetraacetate
- lambda2-lead(2+) ion tetraacetate
- Lead(IV)acetate
- lead(2+), tetraacetate
- plumbous, tetraacetate
- Acetic acid lead(4+) salt (4:1)
- C8H12O8Pb-2
- Acetic acid, lead(4+) salt (4:1)
Physical and chemical properties
Measured values and descriptors computed from the structure
Physical and chemical properties
Measured values, check the supplier specification for your grade
| Appearance | Colorless monoclinic prisms from glacial acetic acidexp.Measured value |
|---|---|
| Odour | LIKE ACETIC ACID OR VINEGARexp.Measured value |
| Melting point | 175 to 180exp.Measured value |
| Density | 2.228 at 17 °C/4 °Cexp.Measured value |
| Solubility | Soluble in hot glacial acetic acid, benzene, chloroform, tetrachloroethane, nitrobenzene.exp.Measured value |
Values vary by grade. Ask suppliers for the COA or TDS of the batch you buy.
Computed descriptors
Calculated from the structure, useful for screening and formulation
| Molecular weight | 443.38 g/molcalc.Computed value |
|---|---|
| Exact mass | 444.031 Dacalc.Computed value |
| LogP (octanol/water) | -5.36calc.Computed value |
| Topological polar surface area | 160.5 Ųcalc.Computed value |
| Hydrogen bond donors | 0calc.Computed value |
| Hydrogen bond acceptors | 8calc.Computed value |
| Rotatable bonds | 0calc.Computed value |
| Heavy atoms | 17calc.Computed value |
| Rings | 0calc.Computed value |
| Aromatic rings | 0calc.Computed value |
| Fraction sp3 carbons | 0.5calc.Computed value |
| Formal charge | -2calc.Computed value |
| Stereocentres | 0calc.Computed value |
| Components | 5calc.Computed value |
| Lipinski rule of five | Passes (0 violations)calc.Computed value |
Calculated for screening. Confirm critical figures with the supplier.
Safety and hazards
GHS classification summary, not a safety data sheet
Hazard statements
- H302 + H332Harmful if swallowed. Harmful if inhaled.
- H302Harmful if swallowed.
- H332Harmful if inhaled.
- H360May damage fertility or the unborn child.
- H360DfMay damage the unborn child. Suspected of damaging fertility.
- H373May cause damage to organs through prolonged or repeated exposure.
- H400Very toxic to aquatic life.
- H410Very toxic to aquatic life with long lasting effects.
Precautionary statements (17)
- P203Obtain, read and follow all safety instructions before use.
- P260Do not breathe dust, fume, gas, mist, vapours or spray.
- P261Avoid breathing dust, fume, gas, mist, vapours or spray.
- P264Wash skin thoroughly after handling.
- P270Do not eat, drink or smoke when using this product.
- P271Use only outdoors or in a well-ventilated area.
- P273Avoid release to the environment.
- P280Wear protective gloves, protective clothing, eye protection and face protection.
- P301 + P317If swallowed: Get medical help.
- P304 + P340If inhaled: Remove person to fresh air and keep comfortable for breathing.
- P317Get medical help.
- P318If exposed or concerned, get medical advice.
- P319Get medical help if you feel unwell.
- P330Rinse mouth.
- P391Collect spillage.
- P405Store locked up.
- P501Dispose of contents and container in accordance with local regulations.
- UN number
- UN 2291
GHS classification summary, not a safety data sheet (SDS). Classifications can differ by supplier, grade and concentration. Always check the supplier's SDS.
Full safety data and first aidLead tetraacetate suppliers
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- India, Valsad ManufacturerUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- IndiaUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- IndiaUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- India, MumbaiUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- ManufacturerUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- Canada, Guelph ManufacturerUnclaimed profileLead(IV) acetateGrade, purity and minimum order on requestPrice on request
- Japan, TokyoUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
- China, ChangshaUnclaimed profileLead tetraacetateGrade, purity and minimum order on requestPrice on request
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Lead tetraacetate price
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Uses and applications
What the substance is used for, by industry and function
Often used as an oxidizing agent in organic syntheses because it is highly selective in cleaving vicinal glycols. It also readily cleaves alpha-hydroxy acids, such as oxalic acid, at room temperature. Another use is for the introduction of acetoxy groups in organic molecules.
Industries and functions
Roles
- oxidising agent
How it is made
Prepd from Pb3O4 and glacial acetic acid preferably in the presence of some acetic anhydride, ... Prepn by electrolysis.[The Merck Index, Fourteenth Edition (2006)
Prepared by adding warm, anhydrous, glacial acetic acid to red lead (Pb3O4) and subsequently cooling the solution.
Regulatory status
Inventories, regulations and trade controls that list this substance
United States
- TSCA inventory (USA)Status: Active in US commerce
HS code and trade data
Customs classification and reported world trade statistics
Global trade
World import and export statistics for the HS code Lead tetraacetate is traded under.
Acetic acid and its salts, acetic anhydride, other
- China28.0%
- Netherlands25.4%
- Germany11.4%
- United States17.0%
- Malaysia13.3%
- Germany7.3%
The HS code shown for Lead tetraacetate is indicative (it was assigned by structure rules). Confirm the classification with your customs broker before shipping.
Frequently asked questions
Quick answers about Lead tetraacetate, based on the data on this page
What is Lead tetraacetate?
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Guides for buyers
Practical guides that help when you source, ship or handle Lead tetraacetate
- Guide, SafetyHow to read a safety data sheet in 10 minutesA section by section method to pull the essentials out of any 16 section SDS: identity, hazards, composition, storage, PPE, properties, transport and emergency measures.Read
- Guide, Trade and logisticsShipping dangerous goods: UN numbers, classes and packing groupsHow the UN dangerous goods system works for chemicals, from the nine classes and UN numbers to packing groups, UN packaging marks, labels, documents and segregation.Read
- Guide, SafetyGHS pictograms, signal words and hazard statements explainedA practical guide to the nine GHS pictograms, the signal words Danger and Warning, H and P statements, and how to read a chemical label in seconds.Read
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